547768-61-6

Basic information

• Product Name: Boranamine, 1-(4-methoxyphenyl)-N,N-bis(1-methylethyl)-
• CAS NO: 547768-61-6
• Molecular Formula: C13H22BNO
• Molecular Weight: 219.135
• Mol File: 547768-61-6.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Boranamine, 1-(4-methoxyphenyl)-N,N-bis(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Boranamine, 1-(4-methoxyphenyl)-N,N-bis(1-methylethyl)-(547768-61-6)
• EPA Substance Registry System: Boranamine, 1-(4-methoxyphenyl)-N,N-bis(1-methylethyl)-(547768-61-6)

Safety Data

• Hazardous Substances Data: 547768-61-6(Hazardous Substances Data)

Upstream product

• 55124-35-1 diisopropylamine borane 
• 623-12-1 4-chloromethoxybenzene 
• 696-62-8 para-iodoanisole 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 22092-92-8 diisopropopylaminoborane 
• 459-64-3 4-methoxybenzenediazonium tetrafluoroborate 
• 108-18-9 diisopropylamine 
• 104-94-9 4-methoxy-aniline 
• 7632-00-0 sodium nitrite 
• 878791-05-0 N,N-diisopropylamine-borane 

Downstream Products

• 7294-51-1 2,4,6-tris(4-methoxyphenyl)boroxine 
• 171364-79-7 2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 53040-92-9 4-(4-tolyl)anisole 

Relevant articles and documents

Borinic Acids via Direct Arylation of Amine-Borane Complexes: An Air- and Water-Stable Boron Source

A synthesis of borinic acids and borinates was optimized using amine-borane complexes as a water and air insensitive borylating agent. The reaction operates under convenient conditions using a non-cryogenic temperature and with no flash chromatography, and it gives no boron impurities. The reaction proceeds through a tandem dehydrogenation-double addition mechanism.

Amine-borane complexes: Air- and moisture-stable partners for palladium-catalyzed borylation of aryl bromides and chlorides

A method for using amine-borane complexes directly in palladium catalyzed borylation has been developed. The reaction proceeds through the sequential formation of a boronium species followed by deprotonation leading to the aminoborane. This reagent is then directly used in the borylation process leading, after work-up, to various boronic acid derivatives. The reaction was applied to (hetero)aryl triflates, iodides, bromides and chlorides.

Method for preparing aminoarylborane compounds or derivatives thereof

The present invention provides a process for the preparation of aminoarylborane compounds and derivatives thereof comprising a step of arylation by reacting an aryl chloride with an aminoborane compound in the presence of a catalytic system. Typically, th