56741-25-4

Basic information

• Product Name: 1-Propanone, 1-phenyl-3-(2-pyridinyl)-
• CAS NO: 56741-25-4
• Molecular Formula: C14H13NO
• Molecular Weight: 211.263
• Mol File: 56741-25-4.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 1-phenyl-3-(2-pyridinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 1-phenyl-3-(2-pyridinyl)-(56741-25-4)
• EPA Substance Registry System: 1-Propanone, 1-phenyl-3-(2-pyridinyl)-(56741-25-4)

Safety Data

• Hazardous Substances Data: 56741-25-4(Hazardous Substances Data)

Upstream product

• 35549-47-4 2-(2-Cyanoethyl)pyridine 
• 110-86-1 pyridine 
• 29526-96-3 1-phenylcyclopropan-1-ol 
• 95837-63-1 (Z)-tert-butyldimethyl((1-phenylprop-1-en-1-yl)oxy)silane 
• 100-69-6 2-vinylpyridine 
• 586-98-1 2-Hydroxymethylpyridine 
• 98-86-2 acetophenone 
• 21035-59-6 N-methyl-2-pyridinemethanamine 
• 3731-51-9 2-(Aminomethyl)pyridine 
• 98-85-1 1-Phenylethanol 
• 1121-60-4 pyridine-2-carbaldehyde 
• 20890-12-4 (E)-1-phenyl-3-(pyridin-2-yl)prop-2-en-1-one 
• 100-52-7 benzaldehyde 
• 65-85-0 benzoic acid 

Downstream Products

• 88644-76-2 1,1-diphenyl-3-[2]pyridyl-propan-1-ol 
• 71858-76-9 1-methyl-2-(2-benzoylethyl)pyridinium iodide 
• 3558-24-5 1-methyl-2-phenyl-1H-indole 
• 118947-82-3 3-hydroxy-3-phenyl-1,2,3,4-tetrahydroquinoline 
• 118947-81-2 1-methyl-4-methylamino-2-phenylindole 

Relevant articles and documents

Electrochemical benzylic oxidation of C-H bonds

Oxidized products have become increasingly valuable as building blocks for a wide variety of different processes and fine chemistry, especially in the benzylic position. We report herein a sustainable protocol for this transformation through C-H functionalization and is performed using electrochemistry as the main power source and tert-butyl hydroperoxide as the radical source for the C-H abstraction. The temperature conditions reported here do not increase above 50 °C and use an aqueous-based medium. A broad substrate scope is explored, along with bioactive molecules, to give comparable and increased product yields when compared to prior reported literature without the use of electrochemistry.

Visible-Light-Promoted Photocatalyst-Free Hydroacylation and Diacylation of Alkenes Tuned by NiCl2·DME

Herein, we describe a visible light-promoted hydroacylation strategy that facilitates the preparation of ketones from alkenes and 4-acyl-1,4-dihydropyridines via an acyl radical addition and hydrogen atom transfer pathway under photocatalyst-free conditions. The efficiency was highlighted by wide substrate scope, good to high yields, successful scale-up experiments, and expedient preparation of highly functionalized ketone derivatives. In addition, this protocol allows for the synthesis of 1,4-dicarbonyl compounds through alkene diacylation in the presence of NiCl2·DME.

Photocatalytic decarboxylative coupling between α-oxocarboxylicacids and alkenes

Photocatalytic decarboxylative cross-coupling which achieves the derivatization of widespread organic acids has become a hot topic in organic synthesis. As special acids, α-oxocarboxylicacids show the great potential in running decarboxylation to construc