575465-42-8

Basic information

• Product Name: 2-Oxazolidinone, 3-[(E)-(2,2-dimethoxyethylidene)amino]-4-(phenylmethyl)-, (4S)-
• CAS NO: 575465-42-8
• Molecular Formula: C14H18N2O4
• Molecular Weight: 278.308
• Mol File: 575465-42-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Oxazolidinone, 3-[(E)-(2,2-dimethoxyethylidene)amino]-4-(phenylmethyl)-, (4S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxazolidinone, 3-[(E)-(2,2-dimethoxyethylidene)amino]-4-(phenylmethyl)-, (4S)-(575465-42-8)
• EPA Substance Registry System: 2-Oxazolidinone, 3-[(E)-(2,2-dimethoxyethylidene)amino]-4-(phenylmethyl)-, (4S)-(575465-42-8)

Safety Data

• Hazardous Substances Data: 575465-42-8(Hazardous Substances Data)

Upstream product

• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 51673-84-8 dimethoxyacetaldehyde 
• 299216-13-0 (S)-3-amino-4-benzyl-1,3-oxazolan-2-one 

Relevant articles and documents

Diastereoselective intermolecular addition of the 1,3-dioxolanyl radical to N-acyl aldohydrazones. Asymmetric synthesis of α-amino acid derivatives

(Matrix presented) N-Acyl aldohydrazones I (R = CO2Et, alkyl, aryl, and furyl) efficiently trap the 1,3-dioxolanyl radical intermolecularly without external activation at temperatures as low as -78°C. For alkyl aldohydrazones, good diastereoselectivities are obtained in the presence of InCl3 at low temperature. Elaboration of the adducts (II) allows for the asymmetric synthesis of α-amino acid derivatives.