58280-04-9

Basic information

• Product Name: (4-benzylphenyl)(phenyl)methanone
• Synonyms: (4-benzylphenyl)(phenyl)methanone
• CAS NO: 58280-04-9
• Molecular Weight: 272.346
• Mol File: 58280-04-9.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (4-benzylphenyl)(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (4-benzylphenyl)(phenyl)methanone(58280-04-9)
• EPA Substance Registry System: (4-benzylphenyl)(phenyl)methanone(58280-04-9)

Safety Data

• Hazardous Substances Data: 58280-04-9(Hazardous Substances Data)

Upstream product

• 793-23-7 1,4-dibenzylbenzene 
• 108-94-1 cyclohexanone 
• 82639-40-5 p-benzylbenzohydrol 
• 100-44-7 benzyl chloride 
• 134-85-0 4-chlorobenzophenone 
• 32752-54-8 4-(bromomethyl)benzophenone 
• 1619239-53-0 1-(4-benzoylbenzyl)tetrahydro-1H-thiophen-1-ium tetraphenylborate 
• 31688-74-1 p-PhC(O)C₆H₄NMe₃(+)*I(-) 
• 89523-63-7 benzylzinc chloride 
• 530-44-9 4-(Dimethylamino)benzophenone 
• 876-08-4 p-(chloromethyl)benzoyl chloride 
• 98-80-6 phenylboronic acid 
• 101-81-5 Diphenylmethane 
• 98-88-4 benzoyl chloride 

Downstream Products

• 82639-41-6 bis<α-(p-benzylphenyl)benzyl>ether 
• 82639-42-7 α,α'-diphenyl-α-bromo-p-xylene 
• 643001-27-8 [4-(bromo-phenyl-methyl)-phenyl]-phenyl-methanone 
• 3016-97-5 1,4-dibenzoylbenzene 
• 82639-40-5 p-benzylbenzohydrol 
• 56430-97-8 4-Benzyl-α-ethyl-benzhydrol 

Relevant articles and documents

Selective electrochemical oxidation of aromatic hydrocarbons and preparation of mono/multi-carbonyl compounds

A selective electrochemical oxidation was developed under mild condition. Various mono-carbonyl and multi-carbonyl compounds can be prepared from different aromatic hydrocarbons with moderate to excellent yield and selectivity by virtue of this electrochemical oxidation. The produced carbonyl compounds can be further transformed into α-ketoamides, homoallylic alcohols and oximes in a one-pot reaction. In particular, a series of α-ketoamides were prepared in a one-pot continuous electrolysis. Mechanistic studies showed that 2,2,2-trifluoroethan-1-ol (TFE) can interact with catalyst species and generate the corresponding hydrogen-bonding complex to enhance the electrochemical oxidation performance. [Figure not available: see fulltext.]

Ligand-Facilitated Reductive Coupling of Benzyl Chlorides with Aryl Chlorides Catalyzed by Well-Defined Heteroleptic Ni (II)-NHC Complexes

Novel heteroleptic Ni (II) complexes bearing a highly hindered yet flexible IPr* ligand, Ni (IPr*)(PPh3)Br2 (1) and Ni (IPr*)(PCy3)Br2 (2) (IPr* = 1,3-bis(2,6-bis (diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene), were easily prepared in 78percent and 89percent yield, respectively. Both were characterized by elemental analysis and NMR spectroscopy, and 1 was subjected to X-ray crystallography. Compared with 2 and its analogue bearing a less sterically demanding IPr ligand (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene), complex 1 exhibited superior catalytic activity in the magnesium-mediated reductive coupling of benzyl chlorides with aryl chlorides, featuring outstanding tolerance of both coupling partners with steric demand. This study discloses a ligand-facilitated reductive coupling of benzyl chlorides with aryl chlorides, which provides a new and practical synthetic tool for the synthesis of diarylmethanes.

Metal-free carbon-carbon cross-couplings between the ion pairs in sulfonium tetraphenylborates

A series of sulfonium tetraphenylborates can be readily prepared by the metathesis of sulfonium halides with sodium tetraphenylborates. After heating at 120-150 °C, the sulfonium tetraphenylborates can smoothly undergo the cross-couplings between the tetraphenylborate anions and the sulfonium cations in the absence of a metal catalyst. For carbonylmethyl-, benzyl-, and allylsulfoniums, the corresponding carbonylmethyl-phenyl, benzyl-phenyl, and allyl-phenyl cross-coupling products can be obtained in 22-76% yields. An interionic electron-transfer mechanism for this cross-coupling reaction is proposed.