58443-71-3

Basic information

• Product Name: S-PHENYL THIOISOBUTYRATE)
• Synonyms: S-PHENYL THIOISOBUTYRATE)
• CAS NO: 58443-71-3
• Molecular Formula: C₁₀H₁₂OS
• Molecular Weight: 180.26668
• Mol File: 58443-71-3.mol
• Article Data: 18

Chemical Properties

• Boiling Point: 260.73°C at 760 mmHg
• Flash Point: 104.591°C
• Appearance: /
• Density: 1.056 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.012mmHg at 25°C
• Refractive Index: 1.55
• CAS DataBase Reference: S-PHENYL THIOISOBUTYRATE)(CAS DataBase Reference)
• NIST Chemistry Reference: S-PHENYL THIOISOBUTYRATE)(58443-71-3)
• EPA Substance Registry System: S-PHENYL THIOISOBUTYRATE)(58443-71-3)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• Hazardous Substances Data: 58443-71-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H12OS/c1-8(2)10(11)12-9-6-4-3-5-7-9/h3-8H,1-2H3

Upstream product

• 108-98-5 thiophenol 
• 79-30-1 isobutyryl chloride 
• 16883-61-7 trimethylsilyl isobutyrate 
• 4551-15-9 phenylthiotrimethylsilane 
• 10557-67-2 N-nitroso-p-methyl-acetanilide 
• 83078-46-0 2-Methyl-dithiopropionsaeure-phenylester 
• 13464-19-2 phenyl chlorothioformate 
• 1068-55-9 isopropylmagnesium chloride 
• 2973-86-6 lithium thiophenoxide 
• 930-69-8 sodium thiophenolate 
• 1192-40-1 copper(I) thiophenolate 
• 981-18-0 triphenyl(phenylazo)methane 
• 79-31-2 isobutyric Acid 
• 78-84-2 isobutyraldehyde 

Downstream Products

• 15621-60-0 isobutyryl-coenzyme A 
• 131436-04-9 4-(2-phenylethyl)-3,3,4-trimethyloxetan-2-one 
• 5463-82-1 2-methyl-3-decanone 
• 611-70-1 phenyl isopropyl ketone 
• 83078-46-0 2-Methyl-dithiopropionsaeure-phenylester 
• 174576-52-4 (R)-4-((S)-1-Benzyloxy-ethyl)-3,3-dimethyl-oxetan-2-one 
• 183050-86-4 C₆H₅S₄^(1-) 
• 52411-62-8 phenyl 3-hydroxy-2,2-dimethyl-3-phenylpropanethioate 
• 153035-87-1 2-methyl-1-trimethylsiloxy-1-phenylthio-1-propene 

Relevant articles and documents

Pd-Catalyzed Double-Decarbonylative Aryl Sulfide Synthesis through Aryl Exchange between Amides and Thioesters

We report the palladium-catalyzed double-decarbonylative synthesis of aryl thioethers by an aryl exchange reaction between amides and thioesters. In this method, amides serve as aryl donors and thioesters are sulfide donors, enabling the synthesis of valuable aryl sulfides. The use of Pd/Xantphos without any additives has been identified as the catalytic system promoting the aryl exchange by C(O)-N/C(O)-S cleavages. The method is amenable to a wide variety of amides and sulfides.

Manganese(iii)-promoted thiocarbonylation of alkylborates with disulfides: synthesis of aliphatic thioesters

A Mn(iii)-promoted thiocarbonylation procedure toward the synthesis of thioesters has been developed. By employing easily available disulfides and potassium alkyltrifluoroborates as the starting materials, and cheap and non-toxic Mn(OAc)3·2H2O as the promotor, a broad range of thioesters were synthesized in good to excellent yieldsviaradical intermediates.

Beta-lactones as antibacterial agents

The present invention relates to specific beta-lactone compounds and compositions thereof for the treatment of infections, such as, e.g., infections with bacteria or infections with protozoa, in particular infections with Gram-positive and/or Gram-negativ