59066-59-0Relevant articles and documents
-
Haering et al.
, p. 1339,1341 (1954)
-
Metal-free oxidative olefination of primary amines with benzylic C-H bonds through direct deamination and C-H bond activation
Gong, Liang,Xing, Li-Juan,Xu, Tong,Zhu, Xue-Ping,Zhou, Wen,Kang, Ning,Wang, Bin
supporting information, p. 6557 - 6560 (2014/08/18)
An oxidative olefination reaction between aliphatic primary amines and benzylic sp3 C-H bonds has been achieved using N-bromosuccinimide as catalyst and tert-butyl hydroperoxide as oxidant. The olefination proceeds under mild metal-free conditions through direct deamination and benzylic C-H bond activation, and provides easy access to biologically active 2-styrylquinolines with (E)-configuration. This journal is the Partner Organisations 2014.
