59184-20-2

Basic information

• Product Name: Silane, [(2-bromophenyl)methoxy]trimethyl-
• CAS NO: 59184-20-2
• Molecular Formula: C10H15BrOSi
• Molecular Weight: 259.218
• Mol File: 59184-20-2.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Silane, [(2-bromophenyl)methoxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(2-bromophenyl)methoxy]trimethyl-(59184-20-2)
• EPA Substance Registry System: Silane, [(2-bromophenyl)methoxy]trimethyl-(59184-20-2)

Safety Data

• Hazardous Substances Data: 59184-20-2(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 18982-54-2 o-bromobenzyl alcohol 
• 94236-21-2 1-bromo-2-((methoxymethoxy)methyl)benzene 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 996-50-9 N,N-diethyl-1,1,1-trimethylsilanamine 
• 392717-83-8 1-(benzyloxy)-4-((methoxymethoxy)methyl) benzene 
• 836-43-1 4-benzyloxybenzyl alcohol 
• 850335-71-6 2-bromo-1-[(ethoxymethoxy)methyl]benzene 

Downstream Products

• 61607-84-9 1-bromo-2-dichloromethyl-benzene 
• 17876-97-0 [2-(hydroxymethyl)phenyl]trimethylsilane 
• 6630-33-7 ortho-bromobenzaldehyde 
• 18982-54-2 o-bromobenzyl alcohol 
• 74637-37-9 2,2'-(oxybis(methylene))bis(bromobenzene) 

Relevant articles and documents

Nanoporous Na+-montmorillonite perchloric acid as an efficient and recyclable catalyst for the chemoselective protection of hydroxyl groups

Nanoporous Na+-montmorillonite perchloric acid as a novel heterogeneous reusable solid acid catalyst was easily prepared by treatment of Na+-montmorillonite as a cheap and commercially available support with perchloric acid. The catalyst was characterized using a variety of techniques including X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), energy dispersive X-ray spectroscopy (EDX), pH analysis and determination of the Hammett acidity function. The prepared reagent showed excellent catalytic activity for the chemoselective conversion of alcohols and phenols to their corresponding trimethylsilyl ethers with 1,1,1,3,3,3-hexamethyldisilazane (HMDS) at room temperature. Deprotection of the resulting trimethylsilyl ethers can also be carried out using the same catalyst in ethanol. All reactions were performed under mild and completely heterogeneous reaction conditions in good to excellent yields. The notable advantages of this protocol are: short reaction times, high yields, availability and low cost of the reagent, easy work-up procedure and the reusability of the catalyst during a simple filtration.

Introduction of PEG-SANM nanocomposite as a new and highly efficient reagent for the promotion of the silylation of alcohols and phenols and deprotection of the silyl ethers

Poly (ethylene glycol)-sulfonated sodium montmorillonite (PEG-SANM) nanocomposite was prepared by a simple method and characterized using XRD, TGA, SEM, TEM, and FT-IR techniques. After preparation and characterization, this reagent was used as a highly efficient and reusable solid acid catalyst for the chemoselective silylation of alcohols and phenols and deprotection of the obtained silyl ethers. Themethod offers several advantages including high to excellent yields of the products, short reaction times, easy preparation of the catalyst and easy work-up procedure. In addition, the catalyst can be recycled and reused at least for five times without significant decrease in the catalytic activity.

Tributyltin grafted onto the surface of 3-aminopropyl functionalized γ-Fe2O3 nanoparticles: A magnetically-recoverable catalyst for trimethylsilylation of alcohols and phenols

Bonding of a homogenous tributyltin chloride catalyst on the surface of functionalized magnetic nanoparticles provides a new stable, efficient and magnetically recyclable catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazan un