59684-77-4

Basic information

• Product Name: Methyl (1β,4aα,8aβ)-decahydro-5,5,8a-trimethyl-2-oxonaphthalene-1-carboxylate
• CAS NO: 59684-77-4
• Molecular Weight: 252.354
• Mol File: 59684-77-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methyl (1β,4aα,8aβ)-decahydro-5,5,8a-trimethyl-2-oxonaphthalene-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl (1β,4aα,8aβ)-decahydro-5,5,8a-trimethyl-2-oxonaphthalene-1-carboxylate(59684-77-4)
• EPA Substance Registry System: Methyl (1β,4aα,8aβ)-decahydro-5,5,8a-trimethyl-2-oxonaphthalene-1-carboxylate(59684-77-4)

Safety Data

• Hazardous Substances Data: 59684-77-4(Hazardous Substances Data)

Upstream product

• 118672-99-4 3-oxo-5-(2,6,6-trimethyl-cyclohex-2-enyl)-pentanoic acid methyl ester 

Downstream Products

• 39707-56-7 (+)-zonarone 
• 39707-54-5 (-)-ent-zonarol 
• 108944-90-7 (1S,4aR,8aR)-(+)-1-(2,5-dimethoxyphenyl)methyl-2-oxo-5,5,8a-trimethyldecahydronaphthalene 
• 69880-60-0 (+)-zonarol dimethyl ether 
• 39707-54-5 (+)-zonarol 
• 108944-87-2 (1R,2R,4aR,8aR)-(-)-1-hydroxymethyl-2-hydroxy-5,5,8a-trimethyldecahydronaphthalene 
• 39707-56-7 (+)-zonarone 
• 108944-92-9 (-)-zonarol dimethyl ether 
• 108944-91-8 (1R,4aS,8aS)-(-)-1-(2,5-dimethoxyphenyl)methyl-2-oxo-5,5,8a-trimethyldecahydronaphthalene 
• 59633-92-0 (1S,2S,4aS,8aS)-(+)-1-(p-tosyloxy)methyl-2-hydroxy-5,5,8a-trimethyldecahydronaphthalene 
• 59633-92-0 (1R,2R,4aR,8aR)-(-)-1-(p-tosyloxy)methyl-2-hydroxy-5,5,8a-trimethyldecahydronaphthalene 
• 10207-83-7 (+/-)-13,14,15,16-Tetranor-5β-labdane-8β,12-diol 

Relevant articles and documents

Studies toward synthesis of bioactive labdanes: Efficient synthesis of 9β-carbomethoxy-4 α, 4β, 10β-trimethyl-(trans)- decahydronaphthalen-8-one

Methyl-5-(2′,6′,6′-trimethylcyclohex-2′-enyl) -3-ketopentanoate 10 has been successfully cyclised to 9β-carbomethoxy- 4α,4β,10β-trimethyl-(trans)-decahydro-naphthalen-8-one 1. Out of the different reaction conditions used, stannic chloride in moist dichlo