59771-25-4

Basic information

• Product Name: 1-(4-isobutylphenyl)-2-methylpropan-1-one
• Synonyms: 1-(4-isobutylphenyl)-2-methylpropan-1-one
• CAS NO: 59771-25-4
• Molecular Weight: 204.312
• Mol File: 59771-25-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-(4-isobutylphenyl)-2-methylpropan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-isobutylphenyl)-2-methylpropan-1-one(59771-25-4)
• EPA Substance Registry System: 1-(4-isobutylphenyl)-2-methylpropan-1-one(59771-25-4)

Safety Data

• Hazardous Substances Data: 59771-25-4(Hazardous Substances Data)

Upstream product

• 538-93-2 1-phenyl-2-methylpropane 
• 79-30-1 isobutyryl chloride 
• 78-84-2 isobutyraldehyde 
• 40150-98-9 4-(2-methyl-1-propyl)benzaldehyde 
• 67-56-1 methanol 
• 611-70-1 phenyl isopropyl ketone 

Downstream Products

• 59770-95-5 1-(4-Isobutylphenyl)-isobutanol 
• 868156-68-7 2-bromo-1-[4-(1-bromo-2-methyl-propyl)-phenyl]-2-methyl-propan-1-one 
• 17171-78-7 1,4-diisobutyl-benzene 

Relevant articles and documents

Palladium-Catalyzed Synthesis of α-Methyl Ketones from Allylic Alcohols and Methanol

One-pot synthesis of α-methyl ketones starting from 1,3-diaryl propenols or 1-aryl propenols and methanol as a C1 source is demonstrated. This one-pot isomerization-methylation is catalyzed by commercially available Pd(OAc)2 with H2O as the only by-product. Mechanistic studies and deuterium labelling experiments indicate the involvement of isomerization of allyl alcohol followed by methylation through a hydrogen-borrowing pathway in these isomerization-methylation reactions.

Method for preparing aryl ketone based on iron-catalyzed free radical-free radical coupling reaction such as ketonic acid decarboxylation and fatty aldehyde de-carbonylation

The invention discloses a method for preparing an aryl ketone derivative based on a free radical-free radical cross-coupling reaction such as ketonic acid decarboxylation and fatty aldehyde de-carbonylation. The method comprises the following steps: reacting aryl-substituted ketonic acid with fatty aldehyde under the catalytic action of ferric triacetylacetonate to generate an aryl ketone derivative; the gram-grade reaction can be realized by the method only by using 3mol% of an iron catalyst; and the method has the advantages of no need of consumption of a large amount of a Lewis acid catalyst or a stoichiometric organic metal reagent, mild reaction conditions, one-step reaction, few by-products, wide substrate application range and scalable reaction, and overcomes the defects of large catalyst consumption, insufficient functional group tolerance, many by-products and the like in the prior art.

NEW PHOTOINITIATORS

The invention relates to novel photoinitators of formulae (I), (II), (III), (IV), (V) and (VI) wherein R1 and R2 are each independently of the other C1-C8alkyl; C1-C4alkyl substituted by OH, C1-C4alkoxy, -COO(C1-C8alkyl), (C1-C4alkyl)-COO-, -CN, benzyl, phenyl or by -N(R15)(R16); C3-C6alkerlyl, benzyl, -CH2-C6H4-(C1-C4alkyl) or phenyl; or R1 and R2 together are unbrarched or branched C2-C9alkylene or C3-C6-oxa- or -aza-alkylene; R3, R4, R5 and R6 are each independently of the others hydrogen, C1-C8alkyl, C3-C6alkenyl, benzyl, -CH2-C6H4-(C1-C4alkyl) or phenyl; R3 and R4 together and/or R5 and R6 together are unbranched or branched C2-C9alkylene; A is CI, Br, -O-R9, -N(R11)(R12) or -S-R18, A' is -O-, -NH- or -NR11-; A" is CI, Br, -O-R9, -N(R11)(R12) or -S-R18 or hydrogen, X is -O-R10 or -N(R13)(R14), n is an integer from 1 to 10, preferably an integer from 1 to 4, especially 1, 2 or 3; R7 is a linker; R8 is a bivalent C2-C3alkylele radical.