59871-24-8Relevant articles and documents
An Unprecedented Intramolecular Migration of Carbon Groups from Aluminum to an Adjacent Vinylic Center and Its Application to the Synthesis of Stereodefined Olefins
Miller, Joseph A.
, p. 998 - 1000 (2007/10/02)
Hydroalumination of 1-chloro-1-alkynes by sodium trialkylaluminum hydrides furnishes stereo- and regioselectively the respective (E)-1-chloro-1-alkenylalanates, which, in the presence of NaOMe, undergo a novel 1,2-migration of a carbon group from Al to the adjacent vinylic center to generate a useful synthesis of di- and trisubstituted olefins of defined geometry.