59970-38-6

Basic information

• Product Name: 4-tert-butylphenyl mesylate
• Synonyms: 4-tert-butylphenyl mesylate
• CAS NO: 59970-38-6
• Molecular Weight: 228.312
• Mol File: 59970-38-6.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 4-tert-butylphenyl mesylate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-tert-butylphenyl mesylate(59970-38-6)
• EPA Substance Registry System: 4-tert-butylphenyl mesylate(59970-38-6)

Safety Data

• Hazardous Substances Data: 59970-38-6(Hazardous Substances Data)

Upstream product

• 98-54-4 para-tert-butylphenol 
• 124-63-0 methanesulfonyl chloride 

Downstream Products

• 145208-63-5 3-<4-(1,1-Dimethylethyl)phenyl>thiophene 
• 1233691-86-5 1-(4-(tert-butyl)phenyl)naphthalene 
• 1110656-20-6 3-[4-(1,1-dimethylethylphenyl)pyridine] 
• 64-18-6 formic acid 
• 253185-03-4 tert-butylbenzene 
• 75-75-2 methanesulfonic acid 
• 98-54-4 para-tert-butylphenol 
• 72596-31-7 diethyl (p-(tert-butyl)phenyl)phosphonate 
• 214360-66-4 2-(4-tert-butylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 5998-50-5 2-(4-(tert-butyl)phenyl)benzo[d]oxazole 
• 1262526-27-1 2-(4-t-butylphenyl)-fluoropyridine 1-oxide 
• 4210-32-6 4-tert-butyl benzonitrile 
• 1253189-48-8 1-(tert-butyl)-4-(hex-1-yn-1-yl)benzene 
• 20374-76-9 (E)-1-(4-tert-butylphenyl)-2-phenylethene 

Relevant articles and documents

Palladium-catalyzed buchwald-hartwig amination and Suzuki-Miyaura cross-coupling reaction of aryl mesylates

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Cyanation of unactivated aryl chlorides and aryl mesylates catalyzed by palladium and hemilabile MOP-type ligands

Palladium-catalyzed cyanation of aryl halides and pseudo halides with potassium hexacyanoferrate is described employing the hemilabile, bulky, and electron-rich MOP-type ligands. When the mixture of t-BuOH and H2O was used as the solvent and K2CO3 as the base, the MOP-type ligands showed high efficiency for the palladium-catalyzed cyanation. The effect of ligand structure was studied in detail, and 2-di-tert-butylphosphino-2′-isopropoxy-1,1′-binaphthyl was the more effective for the cyanation. The catalyst system allows the cyanation of unactivated aryl chlorides, and even aryl mesylates to occur in good yields. Furthermore, the reactivity of different arylated reagents in the catalytic system was found to be: ArBr > ArCl >> ArOMs > ArOSO2Im > ArOSO2NMe2.

Palladium-catalyzed borylation of aryl mesylates and tosylates and their applications in one-pot sequential suzuki-miyaura biaryl synthesis

Top of the one-pots! The first palladium-catalyzed borylation of aryl tosylates and mesylates is described. The reaction conditions are mild and provide excellent functional-group compatibility (e.g., R=CN, CHO, COOMe, C(O)R, NH2, or NH-indole; see scheme). Pd/MeO-CM-phos allows one-pot sequential reactions in the preparation of unsymmetrical biaryls. Copyright