6039-59-4

Basic information

• Product Name: METHYL 1-METHOXY-2-NAPHTHOATE
• Synonyms: METHYL 1-METHOXY-2-NAPHTHOATE
• CAS NO: 6039-59-4
• Molecular Formula: C₁₃H₁₂O₃
• Molecular Weight: 216.23
• Product Categories: C12 to C63;Carbonyl Compounds;Esters
• Mol File: 6039-59-4.mol
• Article Data: 20

Chemical Properties

• Melting Point: 127-128 °C
• Boiling Point: 320 °C(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.17 g/mL at 25 °C(lit.)
• Vapor Pressure: 4.69E-05mmHg at 25°C
• Refractive Index: n20/D 1.603(lit.)
• CAS DataBase Reference: METHYL 1-METHOXY-2-NAPHTHOATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 1-METHOXY-2-NAPHTHOATE(6039-59-4)
• EPA Substance Registry System: METHYL 1-METHOXY-2-NAPHTHOATE(6039-59-4)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 6039-59-4(Hazardous Substances Data)

Usage

Description

METHYL 1-METHOXY-2-NAPHTHOATE is an organic compound that serves as a key intermediate in the synthesis of various chemical compounds. It is characterized by its unique chemical structure, which includes a methoxy group and a naphthoate group.

Uses

Used in Chemical Synthesis:
METHYL 1-METHOXY-2-NAPHTHOATE is used as a precursor in the synthesis of naphthopyran derivatives and (3,4-dihydro-3,3-dimethyl-2H-naphtho[2,3-b]pyran-5,10-dione). Its unique chemical structure allows it to be a versatile building block in the creation of complex organic molecules.
Used in Pharmaceutical Industry:
METHYL 1-METHOXY-2-NAPHTHOATE is used as a key intermediate in the synthesis of pharmaceutical compounds. Its ability to form complex molecules makes it a valuable component in the development of new drugs and therapeutic agents.
Used in Research and Development:
METHYL 1-METHOXY-2-NAPHTHOATE is used in research and development for the exploration of new chemical reactions and the synthesis of novel compounds. Its unique properties make it an interesting subject for scientific investigation and potential applications in various fields.

InChI:InChI=1/C13H12O3/c1-15-12-10-6-4-3-5-9(10)7-8-11(12)13(14)16-2/h3-8H,1-2H3

Upstream product

• 59567-96-3 1,3-Dihydro-1,1-dimethoxyisobenzofuran 
• 292638-85-8 acrylic acid methyl ester 
• 77-78-1 dimethyl sulfate 
• 86-48-6 1-hydroxy-2-naphthoic acid 
• 74-88-4 methyl iodide 
• 186581-53-3 diazomethane 
• 948-03-8 1-hydroxy-naphthalene-2-carboxylic acid methyl ester 

Downstream Products

• 127721-17-9 l-p-menth-3-yl 1-methoxy-2-naphthoate 
• 129656-73-1 (-)-menthyl 1-(-)-menthyloxy-2-naphthoate 

Relevant articles and documents

Mass Spectral Evidence for Δ1-Pyrazolines from the 1,3-Dipolar Addition of Diazomethane to 1-Hydroxy-2-Naphthoic Acid and Its Methyl Ester

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Synthesis of 3,3′-(4H,4′H)-spirobi(2H-naphtho[1,2-b]pyran)-6, 6′-dicarboxylic acid and its optical resolution

The synthesis and optical resolution of 3,3′-(4H,4′H)- spirobi(2H-naphtho[1,2-b]pyran)-6,6′-dicarboxylic acid were successfully accomplished. The formation of the spiro skeleton and the bromination of the aromatic ring were easily achieved in the presence of bromine. Optical resolution was achieved by amidation with L-valinol (2-amino-3-methyl-1-butanol) . Copyright

Axially Chiral 1,1'-Binaphthyl-2-Carboxylic Acid (BINA-Cox) as Ligands for Titanium-Catalyzed Asymmetric Hydroalkoxylation

Axially chiral, enantiopure 1,1'-binaphthyl-2-carboxylic acids (BINA-Cox) have recently been introduced as chiral ligands for transition metal catalysis. Together with equimolar, co-catalytic amounts of Ti(OiPr)4 and water they form an in situ catalyst that performs the asymmetric catalytic hydroalkoxylation of 2-allylphenols to 2-methylcoumarans at high temperature (240 °C, microwave heating). The synthesis of reference ligand 2'-MeO-BINA-Cox (L1) has been optimized and performed at molar scale. Synthetic routes have been developed to access a variety of substituted BINA-Cox ligands (>30 examples), which have been tested for ligand effects on the reference asymmetric cyclization of 2-allylphenol. The substrate range of asymmetric catalytic hydroalkoxylation has been explored through systematic substrate structure variations to define scope and limitations of the titanium-catalyzed process. The new substrates 2-(1-vinylcycloalkyl)phenols (1j, 1k), 2-(2-vinylphenyl)propan-2-ol (1t), and 2'-vinyl-[1,1'-biphenyl]-2-ol (1u) are shown to undergo asymmetric catalytic cyclization to benzodihydrofurans and benzo[c]chromene, respectively.

Organometallic complex with benzazole derivatives as a ligand and organic electroluminescent device including the same

Provided is an organometallic complex with benzazole derivatives represented by chemical formula 1 as a ligand. A novel organometallic complex according to the present invention can be used as an organic layer material of an organic electroluminescent dev