604-66-0Relevant articles and documents
Intermediates in the cleavage of endoperoxides
Bauch, Marcel,Klaper, Matthias,Linker, Torsten
supporting information, (2017/03/24)
The decomposition of anthracene endoperoxides has been investigated under various conditions. Thermolyses proceed via radical intermediates and afford anthracenes and rearrangement products, depending on the substitution pattern. Interestingly, not only the O–O but also the C–O bond can be cleaved homolytically. Under basic conditions fragmentations take place, affording anthraquinone, and reactive oxygen species. This mechanism explains the often observed decomposition of endoperoxides during work-up. Finally, an acid-catalyzed cleavage has been observed under release of hydrogen peroxide. The results should be interesting for the mechanistic understanding of peroxide decomposition and the endoperoxides might serve as mild sources of reactive oxygen species for future applications. Copyright
Diene-Substituent Effects on the Rate of the Retro-Diels-Alder Reaction. Cycloreversion Reactivity Varying over a Range of Five Powers of Ten
Chung, Y.-S.,Duerr, Brook F.,Nanjappan, P.,Czarnik, Anthony W.
, p. 1334 - 1336 (2007/10/02)
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