61141-97-7

Basic information

• Product Name: Benzene,1,1'-(1-ethenyl-1,
• Synonyms: Benzene,1,1'-(1-ethenyl-1,;1,1'-(1-Ethenyl-1,3-propanediyl)bisbenzene;3,5-Diphenyl-1-pentene
• CAS NO: 61141-97-7
• Molecular Formula: C₁₇H₁₈
• Molecular Weight: 222.32
• Mol File: 61141-97-7.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 315.3±22.0 °C(Predicted)
• Appearance: /
• Density: 0.973±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzene,1,1'-(1-ethenyl-1,(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene,1,1'-(1-ethenyl-1,(61141-97-7)
• EPA Substance Registry System: Benzene,1,1'-(1-ethenyl-1,(61141-97-7)

Safety Data

• Hazardous Substances Data: 61141-97-7(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 67-68-5 dimethyl sulfoxide 
• 103-63-9 1-phenyl-2-bromoethane 
• 2687-12-9 cinnamyl chloride 
• 3277-89-2 phenethylmagnesium bromide 
• 104-54-1 3-Phenylpropenol 
• 383-35-7 ethyldifluorophenylsilane 
• 163976-61-2 ethyl 5-phenylpent-1-en-3-yl carbonate 
• 38111-44-3 phenylzinc(II) bromide 
• 569672-70-4 1-(2-phenylethyl)prop-2-en-1-yl 2,2,2-trifluoro-1-(trifluoromethyl)ethyl carbonate 
• 75553-23-0 (E)-5-phenyl-2-penten-1-ol 
• 98-80-6 phenylboronic acid 
• 37904-38-4 5-phenylpent-1-en-3-ol 
• 104-53-0 3-phenyl-propionaldehyde 

Relevant articles and documents

Nickel-Catalyzed Direct Coupling of Allylic Alcohols with Organoboron Reagents

The direct coupling of allylic alcohols with arylboronic acids or their derivatives catalyzed by Ni(cod)2 in the presence of a catalytic amount of base has been developed. A wide variety of allylic substrates or arylboronic acids turned out to be applicable to this catalytic system. The present method does not require the use of ligands for stabilizing the nickel catalyst in most cases or additional activators for activation of allylic alcohols.

Cross-coupling reactions of allylic alcohols in water

Palladium-catalyzed cross-coupling reactions of allylic alcohols and arylboronic acids in water are described. The reactions proceeded smoothly in water at reflux using catalytic amounts of [Pd(allyl)Cl]2 and PPh3. Addition of a catalytic amount of a base allowed the reaction to proceed even at lower temperatures.

The Palladium-Catalyzed Cross-Coupling Reaction of Organosilicon Compounds with Allylic Carbonates or Diene Monoxides

The cross-coupling reaction of allylic carbonates with organosilanes was found to proceed without fluoride ion activation under mild conditions by using a coordinatively unsaturated palladium complex as a catalyst.The reaction was assumed to proceed through an allylpalladium alkoxide derived from the allylic carbonate substrate and a palladium(0) species, the alkoxo ligand activating the organosilicon reagent.Likewise, diene monoxides also underwent cross-coupling with alkenyl- and arylfluorosilanes in moderate to high yields.