61413-50-1Relevant articles and documents
Identification and quantification of lignin monomers and oligomers from reductive catalytic fractionation of pine wood with GC × GC – FID/MS
Dao Thi, Hang,Van Aelst, Korneel,Van den Bosch, Sander,Katahira, Rui,Beckham, Gregg T.,Sels, Bert F.,Van Geem, Kevin M.
supporting information, p. 191 - 206 (2022/01/19)
Thorough lignin characterization is vital to understand the physicochemical properties of lignin and to evaluate lignocellulose biorefinery processes. In this study, an in-depth characterization of lignin oil, obtained from reductive catalytic fractionati
Singlet oxygen in the photodegradation of lignin models
Crestini, Claudia,D'Auria, Maurizio
, p. 7877 - 7888 (2007/10/03)
The photochemical oxidation of lignin models in the presence of singlet oxygen was studied. The treatment of the non-phenolic β-O-4 aryl ether derivatives 6, 7, and 8 in the presence of both oxygen and Rose Bengal gave products deriving from a formal β-C-O cleavage formation. By this way. the derivatives 12, 13, and 15 were obtained. The photochemical oxidation of the phenolic β-O-4 aryl ether 9 gave the same type of product confirming that, in this case, the presence of the carbonyl group is not indispensable to have the cleavage reaction. The use of the model compound 10 showed that, when the phenoxy part of the molecule shows a lower reactivity towards singlet oxygen, the oxidation of the phenol moiety to hydroquinone call occur. The photochemical behaviour of these model compounds can be rationalised from a reaction of singlet oxygen with the phenoxy part of the molecule.