616880-27-4

Basic information

• Product Name: [2,4,6-tris(dimethylaminomethyl)phenolato]bis(triphenylphosphine)silver(I)
• CAS NO: 616880-27-4
• Molecular Weight: 896.841
• Mol File: 616880-27-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [2,4,6-tris(dimethylaminomethyl)phenolato]bis(triphenylphosphine)silver(I)(CAS DataBase Reference)
• NIST Chemistry Reference: [2,4,6-tris(dimethylaminomethyl)phenolato]bis(triphenylphosphine)silver(I)(616880-27-4)
• EPA Substance Registry System: [2,4,6-tris(dimethylaminomethyl)phenolato]bis(triphenylphosphine)silver(I)(616880-27-4)

Safety Data

• Hazardous Substances Data: 616880-27-4(Hazardous Substances Data)

Upstream product

• 603-35-0 triphenylphosphine 
• 90-72-2 2,4,6-tris(dimethylaminomethyl)phenol 
• 20667-12-3 silver(l) oxide 

Relevant articles and documents

Silver(I) aryloxide-triphenylphosphine complexes. An assessment of their potential as CVD precursors and the structure of [Ag(OC6H4Me-2)(PPh3)3]·2- MeC6H4OH·C6H5Me

The silver aryloxide-triphenylphoshine complexes [Ag(OR)(PPh3)2] (R=C6H2Cl3-2,4,6 (1), C6H4Me-2 (2) or C6H2(CH2NMe2)3-2,4,6 (3)) and [Ag(OR)(PPh3)3]·ROH (R=Ph (4) or C6H4Me-2 (5)) have been prepared and characterised. Complexes 1, 3 and 5 were tested as precursors for the growth of silver films on glass substrates using an aerosol-assisted chemical vapour deposition method. Although films were produced, they were of poor quality compared to those produced from other silver complexes as precursors. A crystal structure determination of 5 as a toluene solvate shows the o-cresolato ligand to be monodentate and together with the triphenylphosphine ligands generates a distorted tetrahedral array around the silver. The additional o-cresol molecule is hydrogen-bonded to the o-cresolato oxygen atom and not directly bonded to silver.