61693-03-6Relevant articles and documents
Silver(i)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions
Lo, Vanessa Kar-Yan,Zhou, Cong-Ying,Wong, Man-Kin,Che, Chi-Ming
supporting information; experimental part, p. 213 - 215 (2010/05/01)
Silver(i) salts mediated stereospecific transformation of optically active propargylamines to axially chiral allenes with excellent enantioselectivities (17 examples with 96-99% ee; one substrate with 91% ee) without subsequent racemization.