6172-33-4

Basic information

• Product Name: 1,4-diallyloxy-2,5-dichlorobenzene
• Synonyms: 1,4-diallyloxy-2,5-dichlorobenzene
• CAS NO: 6172-33-4
• Molecular Weight: 259.132
• Mol File: 6172-33-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,4-diallyloxy-2,5-dichlorobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-diallyloxy-2,5-dichlorobenzene(6172-33-4)
• EPA Substance Registry System: 1,4-diallyloxy-2,5-dichlorobenzene(6172-33-4)

Safety Data

• Hazardous Substances Data: 6172-33-4(Hazardous Substances Data)

Upstream product

• 824-69-1 2,5-dichloro-1,4-hydroquinone 
• 106-95-6 allyl bromide 

Relevant articles and documents

Two-directional synthesis of 2,6-Dimethylpyrrolo-[2,3-f]indole-4,8-dione by double Claisen rearrangement and nitrene cyclization

Double Claisen rearrangement of the bis-allyl ether of 2,5-dichloro-1,4-hydroquinone, followed by alkene isomerization, oxidation and double chloride displacement with azide gives 2,5-diazido-3,6-dipropenyl-1,4-benzoquinone. Upon heating, a double nitrene cyclization occurs completing a high yielding, two-directional route to the pyrrolo[2,3-f]indole-4,8-dione ring system.