61886-93-9Relevant articles and documents
Synthesis of the smallest axially chiral molecule by asymmetric carbon-fluorine bond activation
Kuehnel, Moritz F.,Schloeder, Tobias,Riedel, Sebastian,Nieto-Ortega, Belen,Ramirez, Francisco J.,Lopez-Navarrete, Juan T.,Casado, Juan,Lentz, Dieter
supporting information; experimental part, p. 2218 - 2220 (2012/05/20)
Enantioselect-DeFluor: Carbon-fluorine bond cleavage by a chiral zirconium complex allows the synthesis of optically active 1,3-difluoroallene for the first time. Its absolute configuration was established by gas-phase vibrational circular dichroism spectroscopy (see picture). Copyright