624732-11-2Relevant articles and documents
Trifluoromethylated amino alcohol as chiral auxiliary for highly diastereoselective and fast Simmons-Smith cyclopropanation of allylic amine
Katagiri, Toshimasa,Iguchi, Naomi,Kawate, Tomomi,Takahashi, Satoshi,Uneyama, Kenji
, p. 1157 - 1160 (2007/10/03)
Three advantages of a trifluoromethylated amino alcohol auxiliary in the Simmons-Smith cyclopropanation of allylic amines are described. The trifluoromethylated amino alcohol auxiliary reduces unwanted side reactions induced by its acidic, and thus less n