62942-25-0

Basic information

• Product Name: Stannane, tributyl(3-fluorophenyl)-
• Synonyms: Stannane,tributyl(3-fluorophenyl)
• CAS NO: 62942-25-0
• Molecular Formula: C18H31FSn
• Molecular Weight: 385.153
• Mol File: 62942-25-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Stannane, tributyl(3-fluorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane, tributyl(3-fluorophenyl)-(62942-25-0)
• EPA Substance Registry System: Stannane, tributyl(3-fluorophenyl)-(62942-25-0)

Safety Data

• Hazardous Substances Data: 62942-25-0(Hazardous Substances Data)

Upstream product

• 372-20-3 3-fluorophenol 
• 17955-46-3 trimethylsilyltributyltin 
• 455-68-5 methyl 3-fluorobenzoate 
• 366-43-8 3-fluorobenzoic acid phenyl ester 
• 935447-39-5 sodium 3-fluorobenzenesulfinate 
• 813-19-4 bis(tri-n-butyltin) 
• 701-27-9 3-fluorobenzene-1-sulfonyl chloride 

Downstream Products

• 127404-67-5 4-(3-fluoro-phenyl)-but-3-enoic acid 
• 136294-96-7 (E)-4-(3-Fluoro-phenyl)-but-2-enoic acid 
• 396-64-5 3,3'-difluoro-biphenyl 
• 42010-79-7 2-(3'-fluorophenyl)-4,6-dimethoxy-1,3,5-triazine 
• 1496-00-0 1-benzyl-3-fluorobenzene 
• 62681-85-0 1-(3-fluorophenyl)-2,2-dimethyl-1-propanone 
• 1193404-18-0 1-adamantyl-3-fluorophenylmethanone 
• 21550-04-9 1-(3-fluorophenyl)butan-1-one 
• 1422446-26-1 2-phenyl-1-(3-fluorophenyl)butan-1-one 
• 703-67-3 6-fluoro-3,4-dihydronaphthalen-1(2H)-one 

Relevant articles and documents

Catalytic Ester to Stannane Functional Group Interconversion via Decarbonylative Cross-Coupling of Methyl Esters

An unprecedented conversion of methyl esters to stannanes was realized, providing access to a series of arylstannanes via nickel catalysis. Various common esters including ethyl, cyclohexyl, benzyl, and phenyl esters can undergo the newly developed decarbonylative stannylation reaction. The reaction shows broad substrate scope, can differentiate between different types of esters, and if applied in consecutive fashion, allows the transformation of methyl esters into aryl fluorides or biaryls via fluororination or arylation.

Ni-Catalyzed Stannylation of Aryl Esters via C?O Bond Cleavage

A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents via Csp2 ?O cleavage is described. This protocol is characterized by its wide scope, including challenging combinations, thus enabling access to versatile building blocks and orthogonal C?heteroatom bond formations.