64743-45-9Relevant articles and documents
Unraveling structure-reactivity relationships in SNV reactions: Kinetics of the reactions of methoxybenzylidenemalononitrile, 2-(methylthiobenzylidene)- 1,3-indandione, 2-(benzylthiobenzylidene)-1,3-indandione, and methyl β-methylthio-α-nitroci
Bernasconi,Ketner,Ragains,Chen,Rappoport
, p. 2155 - 2164 (2007/10/03)
The kinetics of the title reactions were determined in 50% DMSO-50% water (v/v) at 20 °C; n-BuS-, HOCH2CH2S-, and MeO2CCH2S- were used as thiolate ions. The reactions with the th
Lifetimes of iminium ions in aqueous solution
Eldin, Sherif,Jencks, William P.
, p. 4851 - 4857 (2007/10/02)
Iminium cations have been generated in aqueous solution from the solvolysis of anilinothioethers ArN-(CH3)CH2SR at 25 °C. Common ion inhibition of the solvolysis of anilinothioethers was observed when the thiolate anion leaving group
Kinetics of reactions of thiolate ions with α-nitro β-substituted stilbenes in 50% Me2SO-50% water. Observation of the intermediate in nucleophilic vinylic substitution reactions
Bernasconi, Claude F.,Fassberg, Julianne,Killion Jr., Robert B.,Rappoport, Zvi
, p. 3169 - 3177 (2007/10/02)
The kinetics of reactions of the type Ph(LG)C=CPh(NO2) + RS- →Ph(RS)C=CPh(NO2) + LG- were measured in 50% Me2SO-50% water (v/v) at 20 °C. Results on the following leaving group/nucleophile combination