64931-54-0

Basic information

• Product Name: cis-4,5-(1,8-naphtylene)-2-(α-thiobenzoylethylidene)-1,3-dithiolane
• CAS NO: 64931-54-0
• Molecular Weight: 376.567
• Mol File: 64931-54-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-4,5-(1,8-naphtylene)-2-(α-thiobenzoylethylidene)-1,3-dithiolane(CAS DataBase Reference)
• NIST Chemistry Reference: cis-4,5-(1,8-naphtylene)-2-(α-thiobenzoylethylidene)-1,3-dithiolane(64931-54-0)
• EPA Substance Registry System: cis-4,5-(1,8-naphtylene)-2-(α-thiobenzoylethylidene)-1,3-dithiolane(64931-54-0)

Safety Data

• Hazardous Substances Data: 64931-54-0(Hazardous Substances Data)

Upstream product

• 10269-25-7 4-methyl-5-phenyl-1,2-dithiole-3-thione 
• 208-96-8 acenaphthylene 

Relevant articles and documents

CYCLOADDITION OF 4-METHYL-5-PHENYL-1,2-DITHIOLENE-3-THIONE TO ALKENES

Trithiones (4-methyl-5-phenyl-1,2-dithiolene-3-thione) react with strained alkenes (thermally) and with alkenes containing electron-donating substituents (photochemically) by a cycloaddition mechanism with simultaneous opening of the 1,2-dithiolene ring and the formation of 2-(α-thioacylalkylidene)-1,3-dithiolanes.An alkene with an electron-accepting substituent (methacrylonitrile) reacts photochemically.The initial event of the reaction involves -cycloaddition of the olefin at the exocyclic carbon-sulfur double bond.The final products are 4-methyl-5-phenyl-3-(α-cyanoethylidene)-1,2-dithiolene and 4',5-dimethyl-5'-phenyl-5-cyano-1,3-dithiane-4-spiro-3'-(1',2'-dithiolene).