6508-77-6

Basic information

• Product Name: (6Z)-tridec-6-ene
• Synonyms: 6-Tridecene, (Z)-; cis-6-Tridecene; Z-6-Tridecene
• CAS NO: 6508-77-6
• Molecular Formula: C₁₃H₂₆
• Molecular Weight: 182.3455
• Mol File: 6508-77-6.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 232.3°C at 760 mmHg
• Flash Point: 87.2°C
• Density: 0.77g/cm³
• Vapor Pressure: 0.0903mmHg at 25°C
• Refractive Index: 1.439
• CAS DataBase Reference: (6Z)-tridec-6-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (6Z)-tridec-6-ene(6508-77-6)
• EPA Substance Registry System: (6Z)-tridec-6-ene(6508-77-6)

Safety Data

• Hazardous Substances Data: 6508-77-6(Hazardous Substances Data)

Upstream product

• 7642-04-8 cis-2-octene 
• 111-66-0 oct-1-ene 
• 13389-42-9 trans-2-Octene 
• 546-67-8 lead(IV) tetraacetate 
• 544-63-8 n-tetradecanoic acid 
• 71-43-2 benzene 
• 93588-87-5 Phosphoric acid diethyl ester (R)-1-pentyl-oct-2-ynyl ester 
• 62472-81-5 Z-7-tridecenoic acid 
• 64-19-7 acetic acid 
• 93588-86-4 Methanesulfonic acid 1-pentyl-oct-2-ynyl ester 

Relevant articles and documents

Stabilization of long-chain intermediates in solution. octyl radicals and cations

The rearrangements of 1-octyl, 1-decyl and 1-tridecyl intermediates obtained from thermal lead(IV) acetate (LTA) decarboxylation of nonanoic, undecanoic and tetradecanoic acid were investigated experimentally through analysis and distribution of the products. The relationships between 1,5-, 1,6- and possibly existing 1,7-homolytic hydrogen transfer in 1-octyl-radical, as well as successive 1,2-hydride shift in corresponding cation have been computed via Monte-Carlo method. Taking into account that ratios of 1,5-/1,6-homolytic rearrangements in 1-octyl- and 1-tridecyl radical are approximately the same, the simulation shows very low involvement of 1,7-hydrogen rearrangement (1,5-/1,6-/1,7-hydrogen rearrangement = 85:31:1) in 1-octyl radical.

Z/E-Isomerization of Unsaturated Carboxylic Acids during the Kolbe Electrolysis

Z-4-Enoic acids partially isomerize to E-configurated products in the Kolbe electrolysis.The results from methyl and deuterium labelled carboxylic acids 2 and 16 support an isomerization via a reversible ring closure to cyclopropylcarbinyl radicals.The double bonds of Z-N-enoic acids with N>/= 5 fully retain their configuration in the Kolbe electrolysis; for N=6,7 cyclic products are formed to some extent, which is in accord with the reactivity of 5- and 6-alkenyl radicals.