65847-31-6Relevant articles and documents
Organometallic compound, and organic light emitting diode and organic light emitting device including same
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Paragraph 0085; 0090-0093, (2021/05/05)
The present disclosure provides an organometallic compound shown in the specification, and an organic light emitting diode and an organic light emitting display device including the organometallic compound.
A one-pot synthesis of 1, 2 - diaryl benzimidazole and its derivatives
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Paragraph 0148; 0149; 0150; 0151; 0152; 0153; 0154; 0155, (2017/08/25)
The invention discloses a one-pot synthesis method of 1,2-diarylbenzimidazole and derivatives thereof and belongs to the technical field of chemical preparation. The synthesis method comprises the following steps: adding o-phenylenediamine, benzaldehyde and halogeno benzene which are raw materials into a pressure bottle of 50mL according to the ratio of 1:1.2:1, adding a metal catalyst, an alkali, a ligand and an organic solvent, stirring at the temperature of 110-130 DEG C for 16-24 hours to synthesize 1,2-diarylbenzimidazole and derivatives thereof, cooling, filtering, extracting, distilling at a reduced pressure, and carrying out chromatographic separation by using a column to obtain purified products. The one-pot synthesis method disclosed by the invention has the advantages of mild reaction condition, simple post-treatment, high product selectivity and wide substrate expansion range, and in addition, the one-pot synthesis method can be used for constructing polyaryl imidazole compounds and derivatives easily and efficiently.
Conventional and microwave-assisted synthesis of benzimidazole derivatives and their in vitro inhibition of human cyclooxygenase
Secci, Daniela,Bolasco, Adriana,D'Ascenzio, Melissa,Della Sala, Flavio,Yanez, Matilde,Carradori, Simone
, p. 1187 - 1195 (2013/01/15)
A large series of 1,2-diaryl-benzimidazole and 2-aryl-1H-benzimidazole derivatives were synthesized with slight differences using both microwave irradiation and conventional heating methods. Usually higher yields and time reactions reduction were obtained