66280-55-5

Basic information

• Product Name: Diperoxy dodecane diacid(not more than≤42%,containing≥56% sodium sulfate)
• Synonyms: Diperoxy dodecane diacid(not more than≤42%,containing≥56% sodium sulfate);diperoxydodecanedioic acid;DODECANEDIPEROXOIC ACID;diperoxy dodecane diacid, 14-42%, >= 58% inert;Dodecanebis(peroxoic acid);Einecs 266-297-6
• CAS NO: 66280-55-5
• Molecular Formula: C₁₂H₂₂O₆
• Molecular Weight: 262.29948
• EINECS: 266-297-6
• Mol File: 66280-55-5.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 405.7°Cat760mmHg
• Flash Point: 147.9°C
• Appearance: /
• Density: 1.147g/cm³
• Vapor Pressure: 2.84E-08mmHg at 25°C
• Refractive Index: 1.474
• PKA: 7.62±0.40(Predicted)
• CAS DataBase Reference: Diperoxy dodecane diacid(not more than≤42%,containing≥56% sodium sulfate)(CAS DataBase Reference)
• NIST Chemistry Reference: Diperoxy dodecane diacid(not more than≤42%,containing≥56% sodium sulfate)(66280-55-5)
• EPA Substance Registry System: Diperoxy dodecane diacid(not more than≤42%,containing≥56% sodium sulfate)(66280-55-5)

Safety Data

• RIDADR: 3116
• HazardClass: 5.2
• PackingGroup: II
• Hazardous Substances Data: 66280-55-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H22O6/c13-11(17-15)9-7-5-3-1-2-4-6-8-10-12(14)18-16/h15-16H,1-10H2

Upstream product

• 693-23-2 1,12-dodecanedioic acid 

Downstream Products

• 295-17-0 cyclotetradecane 
• 1120-36-1 1-tetradecene 
• 502-72-7 cyclopentadecanone 

Relevant articles and documents

Highly efficient and stable peracid for rapid and selective oxidation of aliphatic amines to oximes

A novel, transition-metal free, rapid approach for selective oxidation of aliphatic and benzylic amines to oximes is described. The dodecanebis(peroxoic acid)-DMF combination efficiently oxidizes various aliphatic amines at 50 °C temperature to give 100% conversion in 20 min with high oxime selectivity. The peroxy acid used here shows exceptional stability at room temperature and is non-shock sensitive in nature, which was confirmed by differential scanning colorimetric (DSC) analysis.

Process for the manufacture of peroxycarboxylic acids

Peroxycarboxylic acids are prepared by the oxidation of a fatty acid with an excess of hydrogen peroxide in the presence of a strong acid catalyst. The yield is improved and the reaction time is reduced by intimately dispersing throughout the reaction mixture an inert water immiscible solvent for the peroxycarboxylic acid. The product may be recovered in crystalline form from the solvent phase.