6642-07-5Relevant articles and documents
Solvent-free synthesis of trisphenols as starting precursors for the synthesis of calix[4]arenes using sulfonated multi-walled carbon nanotubes
Fareghi-Alamdari, Reza,Golestanzadeh, Mohsen,Zekri, Negar
, p. 3400 - 3412 (2016/05/09)
The condensation of phenol derivatives (12 substrates) with 2,6-bis(hydroxymethyl)phenols (BMP) (6 examples) is reported using sulfonated multi-walled carbon nanotubes (SO3H@MWCNTs) under solvent-free conditions as starting precursors for the synthesis of macrocyclic molecules of calix[4]arenes. The new protocol provides a series of trisphenol derivatives (21 examples) in high yields (up to 94%) and relatively short reaction times (15-120 min). Also, direct synthesis of calix[4]arenes from different trisphenols by use of the catalyst was reported (5 examples). Furthermore, the synthesized calix[4]arene was obtained using a one-pot method from simple and easily available starting materials such as p-cresol for the synthesis of 5,11,17,23-tetramethylcalix[4]arene-25,26,27,28-tetraol. Also, in this process SO3H@MWCNTs can be reused for seven runs with almost consistent efficiency and can be recovered by easy filtration.
A liquid crystal display device and method of manufacturing the same
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, (2007/10/13)
A liquid crystal display (LCD) device includes a first substrate having first and second regions thereon, the first region having a step coverage higher than a step coverage of the second region, a second substrate bonded to the first substrate, the second substrate having a first column spacer corresponding to the first region of the first substrate and a second column spacer corresponding to the second region of the first substrate, and a liquid crystal layer between the first and second substrates.
The Synthesis of Hetero-Halogenated Derivatives of Phloroglucide Analogues
Moshfegh, Ali Akbar,Mazandarani, Behnaz,Nahid, Azarmidokht,Hakimelahi, Gholam Hosein
, p. 1229 - 1232 (2007/10/02)
A short synthesis of the title compounds is reported.Most of the compounds prepared were found to be active against a number of pathogenic microorganisms in vitro.