67093-27-0

Basic information

• Product Name: 3,5-dibenzyloxybenzyl chloride
• Synonyms: 3,5-dibenzyloxybenzyl chloride
• CAS NO: 67093-27-0
• Molecular Weight: 338.834
• Mol File: 67093-27-0.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: 3,5-dibenzyloxybenzyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-dibenzyloxybenzyl chloride(67093-27-0)
• EPA Substance Registry System: 3,5-dibenzyloxybenzyl chloride(67093-27-0)

Safety Data

• Hazardous Substances Data: 67093-27-0(Hazardous Substances Data)

Upstream product

• 24131-31-5 3,5-dibenzyloxybenzyl alcohol 
• 28917-43-3 3,5-dibenzyloxybenzoic acid 
• 100-44-7 benzyl chloride 
• 29654-55-5 5-(hydroxymethyl)benzene-1,3-diol 
• 99-10-5 3,5-Dihydroxybenzoic acid 
• 58605-10-0 methyl 3,5-bis(benzyloxy)benzoate 
• 2150-44-9 1-carbomethoxy-3,5-dihydroxybenzene 
• 108-77-0 1,3,5-trichloro-2,4,6-triazine 

Downstream Products

• 78135-72-5 2-(3,5-dibenzyloxybenzyl)-2-pentyl-1,3-dithian 
• 129536-40-9 [3,5-Bis-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-methanol 
• 184219-30-5 C₄₉H₄₃ClO₆ 
• 862806-04-0 1-(3,5-bis-benzyloxy-benzyloxymethyl)-2-methoxy-naphthalene 
• 1073142-67-2 C₃₄H₂₇NO₃ 
• 137472-14-1 methyl 3,5-bis[[3,5-bis(phenylmethoxy)phenyl]methoxy] benzoate 
• 1312750-31-4 N'-(anthracen-9-ylmethylene)-3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzohydrazide 
• 501-36-0 (E)-5-[2-4-(hydroxyphenyl)ethenyl]-1,3-benzenediol 
• 10083-24-6 trans-piceatannol 
• 4721-07-7 oxyresveratrol 
• 79762-35-9 methyl 2-(3,5-bis(benzyloxy)-2-formylphenyl)acetate 
• 1263694-22-9 methyl-2-(3,5-dihydroxy-2-(2-((2R,6R)-6-methyltetrahydro-2H-pyran-2-yl)acetyl)phenyl)acetate 
• 1392302-25-8 methyl 2-(3,5-bis(benzyloxy)-2-(2-((2R,6R)-6-methyltetrahydro-2H-pyran-2-yl)ethanoyl)phenyl)ethanoate 

Relevant articles and documents

Dendritic poly(benzyl ether)-b-poly(N-vinylcaprolactam) block copolymers: Self-organization in aqueous media, thermoresponsiveness and biocompatibility

Four generations of new amphiphilic thermoresponsive linear-dendritic block copolymers (LDBCs) with a linear poly(N-vinylcaprolactam) (PNVCL) block and a dendritic poly(benzyl ether) block are synthesized by atom transfer radical polymerization (ATRP) of N-vinylcaprolactam (NVCL) using dendritic poly(benzyl ether) chlorides as initiators. The copolymers have been characterized by 1H NMR, FTIR, and GPC showing controlled molecular weight and narrow molecular weight distribution (PDI ≤ 1.25). Their self-organization in aqueous media and thermoresponsive property are highly dependent on the generation of dendritic poly(benzyl ether) block. It is observed for the LDBCs that the self-assembled morphology changes from irregularly spherical micelles, vesicles, rod-like large compound vesicles (LCVs), to the coexistence of spherical micelles and rod-like LCVs, as the generation of the dendritic poly(benzyl ether) increases. The results of a cytotoxicity study using an MTT assay method with L929 cells show that the LDBCs are biocompatible.

Synthesis of Curvulone B Using the 2-Chlorobenzyl Protecting Group

A total synthesis of curvulone B has been completed using a Friedel-Crafts reaction and a highly cis-selective intramolecular oxa-Michael addition. The 2-chlorobenzyl protecting group was employed and found to have much greater Lewis acid stability compared to the simple benzyl group.

Supramolecular design for two-component hydrogels with intrinsic emission in the visible region

We report, for the first time, an in situ formation of two-component hydrogels from pyridine derivatives of poly(aryl ether) dendrons and tartaric acid. The two-component system (dendron + acid) undergoes J-type aggregation, leading to fibrillar type self-assembly in THF-water mixture along with blue (470 nm) and green (500 nm) intrinsic emissions. The Royal Society of Chemistry 2013.