67406-90-0

Basic information

• Product Name: Benzenesulfonic acid, 4-methyl-, ethylidenephenylhydrazide
• CAS NO: 67406-90-0
• Molecular Formula: C15H16N2O2S
• Molecular Weight: 288.37
• Mol File: 67406-90-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenesulfonic acid, 4-methyl-, ethylidenephenylhydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonic acid, 4-methyl-, ethylidenephenylhydrazide(67406-90-0)
• EPA Substance Registry System: Benzenesulfonic acid, 4-methyl-, ethylidenephenylhydrazide(67406-90-0)

Safety Data

• Hazardous Substances Data: 67406-90-0(Hazardous Substances Data)

Upstream product

• 935-07-9 acetaldehyde phenylhydrazone 
• 75-07-0 acetaldehyde 
• 100-63-0 phenylhydrazine 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 67406-97-7 N-Butyl-N-(1-phenylhydrazonoethyl)-N'-(p-methoxyphenyl)-harnstoff 
• 127679-96-3 1-Phenyl-6-phenylazo-1,4,5,6-tetrahydropyridazine 
• 127679-98-5 Phenylazo-ethene 
• 67406-96-6 N-Butylacetamid-N'-phenylhydrazon 

Relevant articles and documents

1-PHENYLAZO-1-ALKENES

Aliphatic aldehyde phenylhydrazones 1 were converted into 1-phenylazo-1-alkenes 3 either by the reaction with I2 and pyridine followed by base induced 1,4-elimination of pyridine.HI (Method A), or via N-(4-methylbenzenesulfonyl)-N-phenylhydrazones 7 which undergo 1,4-elimination of p-toluenesulfinic acid upon treatment with KOt-Bu (Method B).Both procedures yield mixtures of configurational isomers of the phenylazo-alkenes EE- and EZ- 3b-3e; Method B is giving rise to the kinetically controlled isomer mixture (EZ-3 predominant), which equilibrates to the thremodynamicratio (EE-3 predominant) as afforded by Method A.