6839-10-7Relevant articles and documents
Bis(2-alkylpyrrolidin-1-yl)methylidenes as chiral acyclic diaminocarbene ligands
Snead, David R.,Inagaki, Sebastien,Abboud, Khalil A.,Hong, Sukwon
scheme or table, p. 1729 - 1739 (2010/06/14)
2-Alkylpyrrolidines were used as building blocks for acyclic diaminocarbenes (ADCs). First, ureas were made from the corresponding amines, and then the ureas were converted to chloroamidiniums. The chloroamidiniums served as direct precursors to ADCs, and
Phosphazene base-promoted functionalization of aryltrimethylsilanes
Suzawa, Koichi,Ueno, Masahiro,Wheatley, Andrew E. H.,Kondo, Yoshinori
, p. 4850 - 4852 (2007/10/03)
The activation of Ar-Si bonds in aryltrimethylsilane was investigated using a catalytic amount of t-Bu-P4 base and selective functionalizations of aryltrimethylsilanes in the absence of strong electron withdrawing groups on the aromatic rings were accomplished. The Royal Society of Chemistry 2006.