69060-55-5

Basic information

• Product Name: Z-oxime de la 1-phenylpentan-1-one
• Synonyms: Z-oxime de la 1-phenylpentan-1-one
• CAS NO: 69060-55-5
• Molecular Weight: 177.246
• Mol File: 69060-55-5.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Z-oxime de la 1-phenylpentan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: Z-oxime de la 1-phenylpentan-1-one(69060-55-5)
• EPA Substance Registry System: Z-oxime de la 1-phenylpentan-1-one(69060-55-5)

Safety Data

• Hazardous Substances Data: 69060-55-5(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 655-25-4 2,2,2-trifluoroacetophenone oxime 
• 98-88-4 benzoyl chloride 
• 698-16-8 benzohydroximoyl chloride 
• 109-92-2 ethyl vinyl ether 
• 78-94-4 methyl vinyl ketone 
• 873-67-6 benzonitrile oxide 
• 1009-14-9 phenyl butyl ketone 

Downstream Products

• 10264-18-3 N-phenylpentanamide 
• 495-40-9 propiophenone 
• 2782-40-3 N-butylbenzamide 
• 68674-47-5 2-phenyl-3-propyl-1H-indole 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 1009-14-9 phenyl butyl ketone 
• 56680-20-7 2,6-diphenyl-3,5-dipropylpyridine 
• 1313539-79-5 C₁₃H₁₇NO₂ 
• 1522130-49-9 C₂₂H₂₅N 
• 1359715-95-9 1-n-butyl-3,4-diphenylisoquinoline 
• 1251472-09-9 C₂₃H₂₄NOP 

Relevant articles and documents

Rhodium(iii)-catalyzed asymmetric [4+1] spiroannulations of: O -pivaloyl oximes with α-diazo compounds

Chiral RhIII catalysts can catalyze the asymmetric [4+1] spiroannulation of O-pivaloyl oximes with α-diazo homophthalimides under redox-neutral and acid/base-neutral conditions, leading to formation of chiral spirocyclic imines as a result of C-H activation and N-O cleavage. The reaction proceeded with high efficiency and features broad substrate scope, mild reaction conditions, and high to excellent enantioselectivities. This journal is

Iron-catalyzed carbonylative cyclization of γ,δ-unsaturated aromatic oxime esters to functionalized pyrrolines

Herein, a new method of iron-catalyzed carbonylative cyclization of γ,δ-unsaturated aromatic oxime esters to functionalized pyrrolines has been developed. By using readily available substrates, 32 examples of functionalized pyrrolines were prepared in moderate to good yields. Notably, examples of reduction and cycloaddition reactions of the obtained product were given as well. This journal is

Carbonylation of tertiary carbon radicals: synthesis of lactams

Herein, we disclose an interesting iron-catalyzed approach for the carbonylation of a tertiary carbon radical. The tertiary carbon radical generated from a 1,5-hydrogen atom transfer can be captured by CO gas smoothly. Various six-membered lactams were constructed chemo-selectively in high yields.