69278-50-8

Basic information

• Product Name: 2-methoxy-2-methyl-1-(p-nitrophenyl)propane
• CAS NO: 69278-50-8
• Molecular Weight: 209.245
• Mol File: 69278-50-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-methoxy-2-methyl-1-(p-nitrophenyl)propane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methoxy-2-methyl-1-(p-nitrophenyl)propane(69278-50-8)
• EPA Substance Registry System: 2-methoxy-2-methyl-1-(p-nitrophenyl)propane(69278-50-8)

Safety Data

• Hazardous Substances Data: 69278-50-8(Hazardous Substances Data)

Upstream product

• 1754-74-1 2-chloro-2-methyl-1-phenylpropane 
• 67-56-1 methanol 
• 69278-42-8 p-(2-chloro-2-methylpropyl)nitrobenzene 
• 1012-18-6 β,β-dimethyl-p-nitrostyrene 

Relevant articles and documents

The Anomalous Reaction of p-Methoxy-β,β-dimethylstyrene with Mercury(II) Acetate in Methanol

The methoxymercurations of β,β-dimethylstyrene (7) and its p-nitro (12) and p-methoxy (13) derivatives with mercury(II) acetate in methanol are regiospecific and give methoxymercuration products in which the methoxy group is on the β-carbon.Demercuration of the adducts from (12) and (13) with alkaline borohydride proceeds normally, but the demercuration of the adduct from (7) gives considerable formation of the diastereoisomeric dimeric products (9a,b).The methoxymercuration product from (13) is surprisingly reactive and gives mercury(I) acetate and the vicinal diether 1,2-dimethoxy-1-(p-methoxyphenyl)-2-methylpropane (17)