69557-52-4

Basic information

• Product Name: 1-(4-chloro-3,5-dimethyl-phenoxy)-propan-2-ol
• CAS NO: 69557-52-4
• Molecular Weight: 214.692
• Mol File: 69557-52-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(4-chloro-3,5-dimethyl-phenoxy)-propan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-chloro-3,5-dimethyl-phenoxy)-propan-2-ol(69557-52-4)
• EPA Substance Registry System: 1-(4-chloro-3,5-dimethyl-phenoxy)-propan-2-ol(69557-52-4)

Safety Data

• Hazardous Substances Data: 69557-52-4(Hazardous Substances Data)

Upstream product

• 88-04-0 4-Chloro-3,5-dimethylphenol 
• 75-56-9 methyloxirane 
• 127-00-4 1-Chloro-2-propanol 
• 857233-36-4 (4-chloro-3,5-dimethyl-phenoxy)-acetone 

Relevant articles and documents

Selective Cross-Dehydrogenative C(sp3)-H Arylation with Arenes

Selective C(sp3)-C(sp2) bond construction is of central interest in chemical synthesis. Despite the success of classic cross-coupling reactions, the cross-dehydrogenative coupling between inert C(sp3)-H and C(sp2)-H bonds represents an attractive alternative toward new C(sp3)-C(sp2) bonds. Herein, we establish a selective inter-and intramolecular C(sp3)-H arylation of alcohols with nondirected arenes that thereby provides a general pathway to access a wide range of β-arylated alcohols, including tetrahydronaphthalen-2-ols and benzopyran-3-ols, with high to excellent chemo-and regioselectivity.