698-91-9Relevant articles and documents
Catalytic dehydrogenation of o-alkylated or o-alkoxylated iodoarenes with concomitant hydrogenolysis
Motti, Elena,Catellani, Marta
experimental part, p. 565 - 569 (2009/05/07)
Palladium-catalyzed dehydrogenation of suitable chains bonded to an ortho position of an iodoarene has been achieved by two methods both involving oxidative addition of the iodoarene to palladium(0) and palladacycle formation under mild conditions.
2-Phenoxypropene as protective reagent of chiral alcohols
Zandbergen,Willems,Van der Marel,Brussee,Van der Gen
, p. 2781 - 2787 (2007/10/02)
2-Phenoxypropene (2) was applied as a novel protective reagent of chiral alcohols, yielding 2-phenoxy-isopropyl (PIP) ethers. Introduction and cleavage of the protective group was achieved under mild conditions.
Organophosphorus Antioxidants. I. Kinetics and Mechanism of the Decomposition of Alkylhydroperoxides by o-Phenylene Phosphites and Phosphates
Schwertlick, K.,Rueger, C.,Noack, R.
, p. 697 - 705 (2007/10/02)
The reaction mechanism of 2-(2,6-di-tert-butyl-4-methyl-phenoxyl)-1,3,2-benzo-dioxaphosphole (1) with cumyl and t-butyl hydroperoxide has been studied kinetically by means of 31P-n.m.r. spectroscopy and high pressure liquid chromatography. 1 reacts with cumyl hydroperoxide to give the corresponding 2-oxide (2) which with more hydroperoxide and/or water forms the open chained phosphate ester 5.This acidic phosphate decomposes hydroperoxide catalytically.The kinetic parameters of the separate reaction steps are given.The ionic mechanism of hydroperoxide decomposition is accompanied by a homolytic one in a minor proportion.