703-18-4Relevant articles and documents
Aryl Fluoroalkyl Sulfoxides: Optical Stability and pKa Measurement
Messara, Amélia,Vanthuyne, Nicolas,Diter, Patrick,Elhabiri, Mourad,Panossian, Armen,Hanquet, Gilles,Magnier, Emmanuel,Leroux, Frédéric R.
supporting information, p. 5019 - 5026 (2021/08/13)
The enantiomeric separation of aryl trifluoromethyl and difluoromethyl sulfoxides was realized via chiral chromatography. The configurational stability of each set of enantiomers was then studied by thermal enantiomerization. The ΔG≠ values obt
Structure and Reactivity of N-Heterocyclic Alkynyl Hypervalent Iodine Reagents
Le Du, Eliott,Duhail, Thibaut,Wodrich, Matthew D.,Scopelliti, Rosario,Fadaei-Tirani, Farzaneh,Anselmi, Elsa,Magnier, Emmanuel,Waser, Jerome
supporting information, p. 10979 - 10986 (2021/06/08)
Ethynylbenziodoxol(on)e (EBX) cyclic hypervalent iodine reagents have become popular reagents for the alkynylation of radicals and nucleophiles, but only offer limited possibilities for further structure and reactivity fine-tuning. Herein, the synthesis o
Optimization and Gram-Scale Preparation of S-Trifluoromethyl Sulfoximines and Sulfilimino Iminiums, Powerful Reagents for the Late Stage Introduction of the CF3 Group
Barthelemy, Anne-Laure,Certal, Victor,Dagousset, Guillaume,Anselmi, Elsa,Bertin, Luc,Fabien, Laurence,Salgues, Bruno,Courtes, Philippe,Poma, Christian,El-Ahmad, Youssef,Magnier, Emmanuel
, p. 704 - 712 (2019/11/19)
S-Trifluoromethyl sulfoximines and S-trifluoromethyl sulfilimino iminiums are important reagents for the electrophilic or radical late-stage introduction of the CF3 group. We disclose in this article a reappraisal of our previous methodologies