7111-75-3Relevant articles and documents
Mechanistic Studies on the Photogenerated Dienol with α-Phenyl-N-tert-Butylnitrones
Pan, Kai,Ho, Tong-Ing
, p. 243 - 247 (2007/10/03)
The mechanism for the photochemical reactions of o-methyl-benzaldehyde (1), o-methyl-acetophenone (2) and o-methyl-benzophenone (3) in the presence of α-phenyl-N-tert-butylnitrone (PBN) to the formation of stable nitroxyl radicals 4-6 is studied. The nitroxyl radical product 6 can also be obtained by the thermolysis of benzocyclobutenol with PBN. Thus, the radical products were derived from a novel and regioselective 4+2 cycloaddition of the photogenerated dienol intermediate with PBN.
Laser-Jet Delayed Trapping: Electron-Transfer Trapping of the Photoenol from 2-Methylbenzophenone
Wilson, R. Marshall,Hannemann, Klaus,Heineman, William R.,Kirchhoff, Jon R.
, p. 4743 - 4745 (2007/10/02)
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