71365-79-2Relevant articles and documents
Iron and Phenol Co-Catalysis for Rapid Synthesis of Nitriles under Mild Conditions
Meng, Hong,Gao, Sen,Luo, Meiming,Zeng, Xiaoming
, p. 4617 - 4623 (2019/07/15)
A mild, scalable, high yielding, and rapid route to access diverse nitriles from aldehyde oxime esters enabled by iron(III) and phenol co-catalysis has been developed. The reaction was performed at room temperature to give nitriles in excellent yield within minutes. Mechanistic studies show that the reaction may proceed through a radical process in which benzoyl aldehyde oxime is not only a substrate, but also an ancillary ligand to support iron salt in the promotion of the transformation.
Directing-group-assisted copper-catalyzed oxidative esterification of phenols with aldehydes
Zheng, Yong,Song, Wei-Bin,Xuan, Li-Jiang
, p. 10834 - 10843 (2015/11/17)
A directing-group-assisted copper-catalyzed oxidative esterification of phenols with aldehydes using TBHP as an oxidant was described. This methodology which showed the advantages of base, ligand free, short routes and functional group tolerance could be used as an alternative protocol for the classical esterification reactions.
Palladium-catalyzed carbonylative synthesis of N-(2-cyanoaryl)benzamides and sequential synthesis of quinazolinones
Wu, Xiao-Feng,Oschatz, Stefan,Sharif, Muhammad,Beller, Matthias,Langer, Peter
supporting information, p. 23 - 29 (2014/01/06)
A convenient procedure for the synthesis of N-(2-cyanoaryl)benzamides has been developed. Using aryl bromides and 2-aminobenzonitriles as the substrates, Mo(CO)6 as the CO source, the desired amides were produced in good yields. Quinazolinones
