73908-63-1

Basic information

• Product Name: <1-²H₂>-p-nitrobenzyl alcohol
• Synonyms: <1-²H₂>-p-nitrobenzyl alcohol
• CAS NO: 73908-63-1
• Molecular Weight: 155.122
• Mol File: 73908-63-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: <1-²H₂>-p-nitrobenzyl alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: <1-²H₂>-p-nitrobenzyl alcohol(73908-63-1)
• EPA Substance Registry System: <1-²H₂>-p-nitrobenzyl alcohol(73908-63-1)

Safety Data

• Hazardous Substances Data: 73908-63-1(Hazardous Substances Data)

Upstream product

• 619-50-1 4-nitrobenzoic acid methyl ester 
• 62-23-7 4-nitro-benzoic acid 
• 14505-17-0 p-nitrobenzylidyne tribromide 
• 122-04-3 4-nitro-benzoyl chloride 
• 94781-50-7 α-deuterio-4-nitro-benzaldehyde 

Downstream Products

• 83327-12-2 p-nitro(α,α-D2)benzyl chloride 
• 73908-64-2 <1-²H₂>-p-nitrobenzyl bromide 
• 73908-57-3 3,4-Dihydro-2-(p-nitrobenzyl-α,α-d2)isoquinolinium bromide 
• 73908-62-0 1,2,3,4-Tetrahydro-2-(p-nitrobenzyl-α,α-d2)isoquinolinium bromide 
• 73908-61-9 1,2,3,4-tetrahydro-2-(p-nitrobenzyl-α,α-d2)isoquinoline 
• 57204-41-8 1-(ethenyl-1-d)-4-nitrobenzene 
• 156027-99-5 O-(α,α-dideuterio-p-nitrobenzyl) N-acetoxybenzohydroxamate 
• 156028-01-2 α,α-dideuterio-p-nitrobenzyl benzohydroxamate 

Relevant articles and documents

Baylis-Hillman mechanism: A new interpretation in aprotic solvents

(Chemical Equation Presented) Using reaction rate data collected in aprotic solvents, we have determined that the Baylis-Hillman rate-determining step is second order in aldehyde and first order in DABCO and acrylate. On the basis of these data, we have p

Reactive Intermediates from the Solvolysis of Mutagenic O-Alkyl N-Acetoxybenzohydroxamates

Mutagenic O-(para-substituted benzyl) N-acetoxybenzohydroxamates undergo acid-catalysed solvolysis in aqueous acetonitrile but three is a change in mechanism from AA11 to E1 on going from para electron-withdrawing substituents to para +M electron-donating groups.The former permit the formation of a discrete nitrenium ion intermediate whereas the latter promote a concerted elimination of a resonance stabilized benzyl carbocation.

Kinetics and Stereochemistry of Elimination of Nitrous Acid from 1-p-Nitrophenyl-2-nitroethyl Derivatives

The eliminations of nitrous acids from the compounds (1) and (6) are E2 processes, which proceed with a large primary kinetic isotope effect and with antiperiplanar stereochemistry.The rate of elimination of HNO2 fom (1) is intermediate between the rate o