74788-58-2

Basic information

• Product Name: (1-Isothiocyanato-2-methyl-propyl)-benzene
• CAS NO: 74788-58-2
• Molecular Weight: 191.297
• Mol File: 74788-58-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1-Isothiocyanato-2-methyl-propyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1-Isothiocyanato-2-methyl-propyl)-benzene(74788-58-2)
• EPA Substance Registry System: (1-Isothiocyanato-2-methyl-propyl)-benzene(74788-58-2)

Safety Data

• Hazardous Substances Data: 74788-58-2(Hazardous Substances Data)

Upstream product

• 75-15-0 carbon disulfide 
• 6668-27-5 2-methyl-1-phenyl-propylamine 

Downstream Products

• 74548-44-0 1-(2-Hydroxy-ethyl)-3-(2-methyl-1-phenyl-propyl)-thiourea 
• 114051-05-7 1-(Diphenylphosphino)-N-(1'-phenyl-2'-methylpropyl)thioformamid 
• 74787-94-3 1-Butyl-1-(2-hydroxy-ethyl)-3-(2-methyl-1-phenyl-propyl)-thiourea 
• 74787-70-5 1-(3-Hydroxy-propyl)-3-(2-methyl-1-phenyl-propyl)-thiourea 
• 74548-46-2 1-Ethyl-1-(2-hydroxy-ethyl)-3-(2-methyl-1-phenyl-propyl)-thiourea 
• 74548-45-1 1-(2-Hydroxy-ethyl)-1-methyl-3-(2-methyl-1-phenyl-propyl)-thiourea 

Relevant articles and documents

Phosphine-Substituted Chelate Ligands, XXV. Diastereoselective Complexation of Chiral Phosphinothioformamides with Remote Asymmetric Centre

For further studies of the diastereoselective complex formation of ambidentate chiral chelating ligands, we prepared the racemic phosphinothioformamides, Ph2P(X)C(S)NHC*HR1R2, with X = 2e- (R1 = Ph, R2 = Et: 1a; R1 = Ph, R2 = iPr: 2a; R1 = Me, R2 = Et: 3a) and X = O (1b, 2b) according to a previously reported route.The coordination of 1a-3a to CpM(CO)3Cl (M = Mo, W) in methanol gives the diastereomeric P,S-chelate complexes, (Mo: 4-6, W :7-9).In solution, epimerisation proceeds to an equilibrium ratio of B/A = 1.5 in case of 4, 5, 7, and 8, but less than 1.1 with 6 and 9.A reduced diastereoselectivity (d.e. 10-20percent) is also observed during the formation of the analogous molybdenum complexes 10a-d with phosphine ligands derived from α-amino acid esters, Ph2PC(S)NHC*H(R)COOMe .The results indicate a significant asymmetric induction despite of the four bond distance of the chiral centres. - Diastereoselectivity, Chiral Phosphinothioformamides, Amino Acid Esters, Remote Asymmetric Centre, Cyclopentadienyl Molybdenum and Tungsten Complexes