7505-92-2Relevant articles and documents
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Nestler,G.,Zbiral,E.
, p. 1156 - 1162 (1971)
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Oxidative Coupling of Diazo and NH4I: A Route to Primary Oxamates and α-Ketoamides
Fang, Shangwen,Li, Jingjing,Wan, Xiaobing,Wang, Hanghang,Zhao, Yanwei,Zheng, Yonggao
, p. 3050 - 3058 (2020/03/23)
A simple and efficient method has been developed for the preparation of primary oxamates and α-ketoamides through the oxidative coupling of diazo compounds and NH4I. Under the optimized reaction conditions, a range of diazoesters and α-diazoketones was explored, and the corresponding products were obtained in moderate to good yields. This protocol is metal-free, is performed under mild conditions, has a wide substrate scope, and offers operational simplicity.
Green preparation method of alpha-keto-amide
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Paragraph 0020-0022, (2019/10/15)
The invention discloses a method for preparing alpha-keto-amide. The method takes alpha-diazo-ketones compound and ammonium iodide as reaction substrates, under the condition of transition metal-freeand alkali-free, takes tert-butyl hydroperoxide (TBHP) a