75990-93-1

Basic information

• Product Name: (E)-4-<2-(3-bromophenyl)ethenyl>pyridine
• Synonyms: (E)-4-<2-(3-bromophenyl)ethenyl>pyridine
• CAS NO: 75990-93-1
• Molecular Weight: 260.133
• Mol File: 75990-93-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-4-<2-(3-bromophenyl)ethenyl>pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-<2-(3-bromophenyl)ethenyl>pyridine(75990-93-1)
• EPA Substance Registry System: (E)-4-<2-(3-bromophenyl)ethenyl>pyridine(75990-93-1)

Safety Data

• Hazardous Substances Data: 75990-93-1(Hazardous Substances Data)

Upstream product

• 108-89-4 picoline 
• 3132-99-8 m-bromobenzoic aldehyde 
• 823-78-9 meta-bromobenzyl bromide 
• 1620-52-6 4-((benzenesulfonyl)methyl)pyridine 
• 15852-73-0 (3-Bromophenyl)methanol 
• 872-85-5 pyridine-4-carbaldehyde 
• 95902-10-6 (3-bromobenzyl)(triphenyl)phosphonium bromide 

Downstream Products

• 141686-03-5 (E)-N-methyl-4-<2-(3-bromophenyl)ethenyl>-1,2,3,6-tetrahydropyridine 
• 29713-99-3 1-methyl-4-[(E)-2-(3-bromophenyl)ethenyl]-pyridinium iodide 

Relevant articles and documents

(E)-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases

An unprecedented base-promoted direct olefination of aryl alcohols with sulfones via a Julia-type reaction has been described. No extra reductants are needed for Julia reaction since alcohols work as double sources of aldehydes and the hydride. Generally high yields were given for both terminal and highly (E)-selective internal olefins.

Flexible N-methyl-4-phenyl-1,2,3,6-tetrahydropyridine analogues: Synthesis and monoamine oxidase catalyzed bioactivation

Eighteen analogues of N-methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP) were synthesized and evaluated as substrates of monoamine oxidase. In general, the flexible analogues, characterized by the presence of a methylene (or ethylene) bridge between the aryl/heteroaryl and tetrahydropyridyl moieties, were better substrates of the enzyme than the conformationally restricted MPTP. It is suggested that the increased oxidative activity of these flexible analogues reflects enhanced binding due to the ability of the C-4-aryl/heteroaryl substituent to gain access to a hydrophobic pocket within the substrate binding site.