76047-24-0

Basic information

• Product Name: (1-methoxy-1-iodoethyl)triethylphosphonium iodide
• Synonyms: (1-methoxy-1-iodoethyl)triethylphosphonium iodide
• CAS NO: 76047-24-0
• Molecular Weight: 430.048
• Mol File: 76047-24-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1-methoxy-1-iodoethyl)triethylphosphonium iodide(CAS DataBase Reference)
• NIST Chemistry Reference: (1-methoxy-1-iodoethyl)triethylphosphonium iodide(76047-24-0)
• EPA Substance Registry System: (1-methoxy-1-iodoethyl)triethylphosphonium iodide(76047-24-0)

Safety Data

• Hazardous Substances Data: 76047-24-0(Hazardous Substances Data)

Upstream product

• 64713-88-8 O-methyl selenoacetate 
• 554-70-1 triethylphosphine 

Downstream Products

• 6493-83-0 2-methoxy-1-phenyl-propan-1-one 
• 513-86-0 3-hydroxy-2-butanon 
• 7017-05-2 triethylmethylphosphonium iodide 

Relevant articles and documents

Chemistry of O-Alkyl Selenoesters. Reaction with Triethylphosphine

The reaction between triethylphosphine and a number of aliphatic and aromatic selenoesters under oxygen-free conditions have been investigated.The purple intermediate formed in the reaction with the aliphatic selenoesters was quenched with atmospheric oxygen and gave the corresponding esters, whereas quenching with methyl iodide gave the corresponding 1-alkoxy-1-iodoalkyltriethylphosphonium iodides (13)-(16).The 1-alkoxy-1-iodoalkyltriethylphosphonium iodides gave the 1-alkoxyalkyltriethylphosphonium iodides (17)-(20) upon treatment with methanol, and treatment with benzaldehyde at -70 deg C gave α-alkoxyalkyl phenyl ketones (22)-(25).The reaction between the selenobenzoates and triethylphosphine gave α-dialkoxy-stilbenes and -dibenzyls.When the reaction was carried out in cyclohexene 7-alkoxy-7-phenylbicycloheptanes were formed.The presence of benzaldehyde in the reaction mixture led to α-alkoxystilbenes.An explanation for these different reactions is presented.