76246-81-6

Basic information

• Product Name: Ethanone, 1-[3,5-dimethoxy-4-(phenylmethoxy)phenyl]-
• CAS NO: 76246-81-6
• Molecular Formula: C17H18O4
• Molecular Weight: 286.328
• Mol File: 76246-81-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-[3,5-dimethoxy-4-(phenylmethoxy)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[3,5-dimethoxy-4-(phenylmethoxy)phenyl]-(76246-81-6)
• EPA Substance Registry System: Ethanone, 1-[3,5-dimethoxy-4-(phenylmethoxy)phenyl]-(76246-81-6)

Safety Data

• Hazardous Substances Data: 76246-81-6(Hazardous Substances Data)

Upstream product

• 30835-78-0 ethyl 3-(4-benzyloxy-3,5-dimethoxyphenyl)-3-oxopropionate 
• 2478-38-8 1-(4-hydroxy-3,5-dimethoxy-phenyl)-ethanone 
• 100-44-7 benzyl chloride 
• 530-57-4 3,5-dimethoxy-4-hydroxybenzoic acid 
• 27065-65-2 methyl 4-benzyloxy-3,5-dimethoxybenzoate 
• 884-35-5 methyl syringate 
• 14588-61-5 4-benzyloxy-3,5-dimethoxybenzoic acid chloride 
• 14588-60-4 4-(benzyloxy)-3,5-dimethoxybenzoic acid 
• 118-41-2 Eudesmic acid 
• 530-59-6 trans-3,5-dimethoxy-4-hydroxycinnamic acid 
• 41628-47-1 ethyl (2E)-3-[4-hydroxy-3,5-bis(methyloxy)phenyl]-2-propenoate 
• 100-39-0 benzyl bromide 
• 20675-96-1 trans-sinapyl alcohol 
• 487-35-4 (+)-syringaresinol 

Downstream Products

• 2478-38-8 1-(4-hydroxy-3,5-dimethoxy-phenyl)-ethanone 
• 58613-51-7 1-(4-Hydroxy-3,5-dimethoxy-phenyl)-2-(4-hydroxy-3-methoxy-phenyl)-propane-1,3-diol 
• 123348-15-2 1-(4-Benzyloxy-3,5-dimethoxy-phenyl)-2-(4-benzyloxy-3-methoxy-phenyl)-propane-1,3-diol 
• 535967-76-1 1-(4-(benzyloxy)-3,5-dimethoxyphenyl)-2-(2-methoxyphenoxy)propane-1,3-diol 
• 92409-34-2 1-(4-hydroxy-3,5-dimethoxyphenyl)-2-(2'-methoxyphenoxy)-1,3-propanediol 
• 65109-39-9 4-(2-(2,6-dimethoxyphenoxy)-1-hydroxyethyl)-2,6-dimethoxyphenol 

Relevant articles and documents

Domino lignin depolymerization and reconnection to complex molecules mediated by boryl radicals

Chemical degradation of lignin has attracted increasing interest due to its potential for producing chemicals from renewable resources. Herein, we present a new transition metal free degradation procedure utilizing DDQ-oxidation and boryl radical mediated degradation, followed by reconnection of a monomer intermediate to a new dimer in a domino process. Our results include the selective degradation of oxidized β-O-4 model compounds by a boryl radical initiated with a catalytic amount of 4-(4-pyridinyl)benzonitrile and bispinacolborane B2(pin)2 as well as its application to organosolv lignin. This sequential procedure expands the toolbox for lignin degradation from simple depolymerization to high-value products by incorporating bond forming transformations within the process, and also provides a new transition-metal free method for the construction of 1,6-diketone fragments.

VO(acac)2 catalyzed oxidative deprotection of oximes, hydrazones, and semicarbazones

Oximes, hydrazones, and semicarbazones undergo facile deprotection in the presence of a catalytic amount of vanadyl acetylacetonate and hydrogen peroxide in acetone at room temperature.