76357-91-0

Basic information

• Product Name: 1-(tert-butyl)-4-(hexyloxy)benzene
• Synonyms: 1-(tert-butyl)-4-(hexyloxy)benzene
• CAS NO: 76357-91-0
• Molecular Weight: 234.382
• Mol File: 76357-91-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-(tert-butyl)-4-(hexyloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(tert-butyl)-4-(hexyloxy)benzene(76357-91-0)
• EPA Substance Registry System: 1-(tert-butyl)-4-(hexyloxy)benzene(76357-91-0)

Safety Data

• Hazardous Substances Data: 76357-91-0(Hazardous Substances Data)

Upstream product

• 67-66-3 chloroform 
• 102-86-3 tri-n-hexylamine 
• 98-54-4 para-tert-butylphenol 
• 111-25-1 1-bromo-hexane 
• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 111-27-3 hexan-1-ol 
• 98-53-3 4-tercbutyl-cyclohexanone 

Downstream Products

• 746652-29-9 2-bromo-4-tert-butyl-1-n-hexyloxybenzene 

Relevant articles and documents

Semiheterogeneous Dual Nickel/Photocatalytic (Thio)etherification Using Carbon Nitrides

A carbon nitride material can be combined with homogeneous nickel catalysts for light-mediated cross-couplings of aryl bromides with alcohols under mild conditions. The metal-free heterogeneous semiconductor is fully recyclable and couples a broad range of electron-poor aryl bromides with primary and secondary alcohols as well as water. The application for intramolecular reactions and the synthesis of active pharmaceutical ingredients was demonstrated. The catalytic protocol is applicable for the coupling of aryl iodides with thiols as well.

Switching on elusive organometallic mechanisms with photoredox catalysis

Transition-metal-catalysed cross-coupling reactions have become one of the most used carbon-carbon and carbon-heteroatom bond-forming reactions in chemical synthesis. Recently, nickel catalysis has been shown to participate in a wide variety of C-C bond-forming reactions, most notably Negishi, Suzuki-Miyaura, Stille, Kumada and Hiyama couplings. Despite the tremendous advances in C-C fragment couplings, the ability to forge C-O bonds in a general fashion via nickel catalysis has been largely unsuccessful. The challenge for nickel-mediated alcohol couplings has been the mechanistic requirement for the critical C-O bond-forming step (formally known as the reductive elimination step) to occur via a Ni(iii) alkoxide intermediate. Here we demonstrate that visible-light-excited photoredox catalysts can modulate the preferred oxidation states of nickel alkoxides in an operative catalytic cycle, thereby providing transient access to Ni(iii) species that readily participate in reductive elimination. Using this synergistic merger of photoredox and nickel catalysis, we have developed a highly efficient and general carbon-oxygen coupling reaction using abundant alcohols and aryl bromides. More notably, we have developed a general strategy to 'switch on' important yet elusive organometallic mechanisms via oxidation state modulations using only weak light and single-electron-transfer catalysts.

Novel sulfonyldiazomethanes, photoacid generators, resist compositions, and patterning process

A chemical amplification type resist composition comprising a specific benzenesulfonyldiazomethane containing a long-chain alkoxyl group at the 2-position on benzene ring has many advantages including improved resolution, improved focus latitude, minimize