77192-24-6

Basic information

• Product Name: Silane, trimethyl(2-methylene-4-phenylbutyl)-
• CAS NO: 77192-24-6
• Molecular Formula: C14H22Si
• Molecular Weight: 218.414
• Mol File: 77192-24-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(2-methylene-4-phenylbutyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(2-methylene-4-phenylbutyl)-(77192-24-6)
• EPA Substance Registry System: Silane, trimethyl(2-methylene-4-phenylbutyl)-(77192-24-6)

Safety Data

• Hazardous Substances Data: 77192-24-6(Hazardous Substances Data)

Upstream product

• 2021-28-5 ethyl dihydrocinnamate 
• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 1822-00-0 trimethylsilylmethyllithium 
• 645-45-4 hydrocinnamic acid chloride 
• 75-77-4 chloro-trimethyl-silane 
• 6683-51-8 2-methyl-4-phenyl-1-butene 
• 2550-26-7 4-Phenyl-2-butanone 

Downstream Products

• 774199-12-1 4-phenyl-2-trimethylsilanylmethyl-butane-1,2-diol 
• 1266145-52-1 C₁₇H₂₂O 
• 1380233-02-2 (5,5,5-trifluoro-3-methylenepentyl)benzene 
• 1448863-22-6 (1R)-3-methylene-5-phenyl-1-m-tolylpentanol 
• 1448863-21-5 (1R)-3-methylene-1-(naphth-2-yl)-5-phenylpentanol 
• 1266145-46-3 C₁₅H₁₈O 
• 192195-29-2 ethyl (2-methylene-4-phenylbutoxy)acetate 
• 192195-17-8 1-diazo-3-(2-methylene-4-phenylbutoxy)-2-propanone 
• 75074-59-8 4-phenyl-2-(hydroxymethyl)but-1-ene 

Relevant articles and documents

Asymmetric counteranion-directed catalytic hosomi-sakurai reaction

Counteranion control enables the enantioselective, organo Lewis acid catalyzed Hosomi-Sakurai reaction of (hetero)aromatic aldehydes and allylsilanes using an easily handled disulfonimide precatalyst (see scheme). The key to the success of this system is to turn the usually undesired silylium ion catalysis into the desired catalytic regime and pair the cation with an enantiopure disulfonimide anion, thereby applying the concept of asymmetric counteranion-directed catalysis.

AN EFFICIENT METHOD FOR CONVERSION OF CARBOXYLIC ACID DERIVATIVES TO ALLYLSILANES

Treatment of acid halides with trimethylsilylmethyl cerium dichloride affords bis β-silylethyl tertiary alcohols which efficiently undergo a trimethylchlorosilane-promoted Peterson reaction to generate allylsilanes in high overall yield.