7731-37-5

Basic information

• Product Name: 2-Benzyl-3-phenyloxaziridine
• Synonyms: 2-Benzyl-3-phenyloxaziridine
• CAS NO: 7731-37-5
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211
• Mol File: 7731-37-5.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 321℃
• Flash Point: 98℃
• Appearance: /
• Density: 1.187
• CAS DataBase Reference: 2-Benzyl-3-phenyloxaziridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Benzyl-3-phenyloxaziridine(7731-37-5)
• EPA Substance Registry System: 2-Benzyl-3-phenyloxaziridine(7731-37-5)

Safety Data

• Hazardous Substances Data: 7731-37-5(Hazardous Substances Data)

Upstream product

• 780-25-6 N-benzylidene benzylamine 
• 100-52-7 benzaldehyde 
• 100-46-9 benzylamine 
• 3376-26-9 N-Benzylidenebenzylamine N-oxide 

Downstream Products

• 50506-90-6 4-benzyl-2-phenyl-5-phenylimino-[1,2,4]thiadiazolidine-3-thione 
• 622-30-0 N-benzyl hydroxylalmine 
• 75934-59-7 N-benzyl-N-nitrosohydroxylamine ammonium salt 
• 1485-70-7 N-benzylbenzamide 
• 100-52-7 benzaldehyde 
• 92-29-5 hydrobenzamide 

Relevant articles and documents

Weak base-promoted selective rearrangement of oxaziridines to amidesviavisible-light photoredox catalysis

The selective rearrangement of oxaziridines to amidesviaa single electron transfer (SET) pathway is unexplored. In this study, we present a weak base-promoted selective rearrangement of oxaziridines to amidesviavisible-light photoredox catalysis. The developed method shows excellent functional group tolerance with a broad substrate scope and good to excellent yields. Furthermore, control experiments and density functional theory (DFT) calculations are performed to gain insight into the reactivity and selectivity.

Iron and manganese (III) - Porphyrins as new applicable catalysts for selective oxidation of imines with urea-hydrogen peroxide

A variety of imines were oxidised with urea-hydrogen peroxide using iron(III) and manganese (III)- tetraphenylporphyrins [Fe(TPP)Cl], [Mn(TPP)Cl] and manganese (III)-octabromotetraphenyl porphyrin [Mn(TPPBr8)Cl] as catalysts. Experimental resul

Synthesis of N-substituted N-nitrosohydroxylamines as inhibitors of mushroom tyrosinase

A series of N-substituted N-nitrosohydroxylamines including six new compounds were synthesized and examined for inhibition of mushroom tyrosinase. Corresponding hydroxylamines were reacted with n-butyl nitrite to give substituted nitrosohydroxylamines as their ammonium salt. The N-substituted hydroxylamines were prepared from the primary amines via the oxaziridine, or from the carbonyl compounds via the oxime. Most of the nitrosohydroxylamines tested inhibited mushroom tyrosinase. Among them, N-cyclopentyl-N-nitrosohydroxylamine exhibited the most potent activity (IC50=0.6 μM), as powerful as that of tropolone, one of the most powerful inhibitors. As removal of nitroso or hydroxyl moiety, the enzyme inhibitory activity was completely diminished. Both N-nitroso group and N-hydroxy group were suggested to be essential for the activity, probably by interacting with the copper ion at the active site of the enzyme. Lineweaver-Burk plotting showed that cupferron was a competitive inhibitor but that N-cyclopentyl-N-nitrosohydroxylamine was not.