78382-15-7Relevant articles and documents
Iridacycles as Catalysts for the Autotandem Conversion of Nitriles into Amines by Hydrosilylation: Experimental Investigation and Scope
Hamdaoui, Mustapha,Desrousseaux, Camille,Habbita, Houda,Djukic, Jean-Pierre
supporting information, p. 4864 - 4882 (2018/02/07)
The set of iridacycles [{C,N}Cp?IrIII-Cl] ({C,N} = benzo[h]quinoline, dibenzo[f,h]quinoline) containing the (pentamethylcyclopentadienyl)iridium(III) unit were synthesized and derivatized into cations [{C,N}Cp?Ir-NCMe]+ associated wi
N-Acetyl-N,N-dipyrid-2-yl (cyclooctadiene) rhodium (I) and iridium (I) complexes: Synthesis, X-ray structures, their use in hydroformylation and carbonyl hydrosilylation reactions and in the polymerization of diazocompounds
Bantu, Bhasker,Wurst, Klaus,Buchmeiser, Michael R.
, p. 5272 - 5278 (2008/02/13)
The synthesis of novel N-acetyl-N,N-dipyrid-2-yl complexes of RhI and IrI, i.e. [RhCl(CH3CONPy2)(COD)] (1) and [IrCl(CH3CONPy2)(COD)] (2), respectively, is described. Upon prolonged treatment in CH2Cl2 at room temperature, complex 1 is transformed into a cationic Rh-complex, i.e. [Rh(CH3CONPy2)(COD)+RhCl2(COD)-] (1a). Compound 1a crystallizes in the monoclinic space group P21/c, complex 2 crystallizes in the triclinic space group P over(1, ?). Compound 1 was investigated for its catalytic activity in the hydroformylation of cyclooctene as well as of 1-octene. In addition, 1 was used in various carbonyl hydrosilylation reactions of both aldehydes and ketones. There, turn-over numbers up to 50 000 and yields in the range of 85-100% were observed. Finally, compound 1 was successfully used for the polymerization of N2CHCOOEt yielding highly stereoregular poly(ethoxycarbonylcarbene) with Mw = 67 000 g/mol and a polydispersity index (PDI) of 2.59.
ORGANOSILICON COMPOUNDS XXIX. REACTIONS OF AROMATIC HYDROXY ALDEHYDES AND HYDROXY KETONES WITH TRIALKYLSILANES
Lapkin, I. I.,Dvinskikh, V. V.
, p. 1147 - 1152 (2007/10/02)
-
