78672-59-0

Basic information

• Product Name: (1,3,3-Trimethyl-bicyclo[2.2.1]hept-2-ylidene)-methanone
• Synonyms: (1,3,3-Trimethyl-bicyclo[2.2.1]hept-2-ylidene)-methanone
• CAS NO: 78672-59-0
• Molecular Weight: 164.247
• Mol File: 78672-59-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1,3,3-Trimethyl-bicyclo[2.2.1]hept-2-ylidene)-methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (1,3,3-Trimethyl-bicyclo[2.2.1]hept-2-ylidene)-methanone(78672-59-0)
• EPA Substance Registry System: (1,3,3-Trimethyl-bicyclo[2.2.1]hept-2-ylidene)-methanone(78672-59-0)

Safety Data

• Hazardous Substances Data: 78672-59-0(Hazardous Substances Data)

Upstream product

• 76275-42-8 O-trimethylsilyl 1,3,3-trimethylbicyclo<2.2.1>heptane-2-thiocarboxylate 

Downstream Products

• 488-97-1 cyclofenchene 
• 471-84-1 fenchene 
• 78672-60-3 7,7-Dimethyl-2-methylene-bicyclo[2.2.1]heptane-1-carbaldehyde 

Relevant articles and documents

Gas-phase Thermolyses. Part 3. Gas-phase Thermolysis of Silylated Thionocarboxylic Acid Derivatives: a Route to Thioketens?

The unimolecular gas-phase thermolytic decomposition of three silylated thionocarboxylic acid derivatives (2b), (3), and (8) have been studied by the flash vacuum thermolysis-field ionization mass spectrometry technique in the temperature range from 783 to 1404 K in order to elucidate its possible applicability as a route to thioketens.Only very minor amounts of the expected thioketens were found, whereas the corresponding ketens were obtained as the major products.A possible mechanism for keten formation is discussed.