79074-00-3Relevant articles and documents
A Tricyclic Hexaphosphane
Bresien, Jonas,Schulz, Axel,Villinger, Alexander
, p. 18543 - 18546 (2015)
The reaction of the functionalized cyclo-tetraphosphane [ClP(μ-PMes)]2 (Mes=2,4,6-tri-tert-butylphenyl) with different Lewis bases led to the formation of an unprecedented tricyclic hexaphosphane, MesP6Mes. The formation of this comp
Low-temperature isolation of the bicyclic phosphinophosphonium salt [Mes?2P4Cl][GaCl4]
Bresien, Jonas,Faust, Kirill,Schulz, Axel,Villinger, Alexander
, p. 6926 - 6930 (2015)
The reaction of [ClP(μ-PMes?)]2 (1) with the Lewis acid GaCl3 yielded a hitherto unknown tetraphosphabicyclo[1.1.0]butan-2-ium salt, [Mes?P4(Cl)Mes?][GaCl4] (3[GaCl4]), which incorporates a positively
3H-Phosphaallenes Revisited: Facile Synthesis by Hydroalumination of Alkynylphosphines and β-Elimination, Stability and Trapping of Transient Species by Coordination to Transition Metal Atoms
Kl?cker, Hans,Tendyck, Jonas C.,Keweloh, Lukas,Hepp, Alexander,Uhl, Werner
, p. 4793 - 4807 (2019/03/13)
A facile method for the efficient synthesis of 3H-phosphaallenes, R?P=C=C(H)?R′, is presented, which comprises treatment of dialkynylphosphines with dialkylaluminium hydrides (hydroalumination) and elimination of aluminium alkynides from intermediate alke
Functional small-molecules & polymers containing P=C and As=C bonds as hybrid π-conjugated materials
Morales Salazar, Daniel,Mijangos, Edgar,Pullen, Sonja,Gao, Ming,Orthaber, Andreas
supporting information, p. 1120 - 1123 (2017/02/05)
Stable phospha- and arsaalkenes were used to synthesize polymers containing unsaturated P=C and As=C moieties. The composition, chemical environment, structure, optical, and electronic properties of the monomers and polymers were elucidated. The incorpora