79698-60-5

Basic information

• Product Name: methyl 4,6-O-benzylidene-2-benzyloxycarbonylamino-2-deoxy-3-O-(N-imidazole-1-sulfonyl)-α-D-glucopyranoside
• Synonyms: methyl 4,6-O-benzylidene-2-benzyloxycarbonylamino-2-deoxy-3-O-(N-imidazole-1-sulfonyl)-α-D-glucopyranoside
• CAS NO: 79698-60-5
• Molecular Weight: 545.57
• Mol File: 79698-60-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 4,6-O-benzylidene-2-benzyloxycarbonylamino-2-deoxy-3-O-(N-imidazole-1-sulfonyl)-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-O-benzylidene-2-benzyloxycarbonylamino-2-deoxy-3-O-(N-imidazole-1-sulfonyl)-α-D-glucopyranoside(79698-60-5)
• EPA Substance Registry System: methyl 4,6-O-benzylidene-2-benzyloxycarbonylamino-2-deoxy-3-O-(N-imidazole-1-sulfonyl)-α-D-glucopyranoside(79698-60-5)

Safety Data

• Hazardous Substances Data: 79698-60-5(Hazardous Substances Data)

Upstream product

• 288-32-4 1H-imidazole 
• 60076-41-7 methyl 4,6-O-benzylidene-2-(benzyloxycarbonyl)amino-2-deoxy-α-D-glucopyranoside 
• 90-76-6 glucosamine 
• 100-52-7 benzaldehyde 

Downstream Products

• 80734-77-6 ((4aR,6S,7S,8S,8aR)-8-Iodo-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-carbamic acid benzyl ester 
• 79698-78-5 (R)-4-Benzenesulfinyl-6-((2R,4S,5R)-4-benzyloxy-5-methyl-tetrahydro-furan-2-yl)-2-((2S,5R,6R)-6-tert-butoxy-5-methyl-tetrahydro-pyran-2-yl)-2-methyl-hexan-3-ol 
• 79698-78-5 (S)-4-Benzenesulfinyl-6-((2R,4S,5R)-4-benzyloxy-5-methyl-tetrahydro-furan-2-yl)-2-((2S,5R,6R)-6-tert-butoxy-5-methyl-tetrahydro-pyran-2-yl)-2-methyl-hexan-3-ol 
• 79698-62-7 Benzoic acid (2R,3S,5R,6S)-5-benzyloxycarbonylamino-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 79712-10-0 (2R,3S,5R)-5-(3-Benzenesulfinyl-propyl)-3-benzyloxy-2-methyl-tetrahydro-furan 
• 79698-70-7 (2R,3S,5R)-3-Benzyloxy-2-methyl-5-(3-phenylsulfanyl-propyl)-tetrahydro-furan 
• 494868-08-5 ((2S,3R,5S,6R)-5-Hydroxy-2-methoxy-6-methyl-tetrahydro-pyran-3-yl)-carbamic acid benzyl ester 
• 79698-67-2 (E)-3-((2S,4S,5R)-4-Benzyloxy-5-methyl-tetrahydro-furan-2-yl)-acrylic acid ethyl ester 
• 79698-69-4 3-((2R,4S,5R)-4-Benzyloxy-5-methyl-tetrahydro-furan-2-yl)-propan-1-ol 
• 79698-65-0 (2R,3S,5S)-3-Benzyloxy-5-dimethoxymethyl-2-methyl-tetrahydro-furan 
• 79698-66-1 (2S,4S,5R)-4-Benzyloxy-5-methyl-tetrahydro-furan-2-carbaldehyde 
• 80667-90-9 methyl 4,6-O-benzylidene-2-benzyloxycarbonylamino-2,3-dideoxy-α-D-ribo-hexopyranoside 
• 79698-61-6 ((2R,4aR,6S,7S,8aR)-8-Iodo-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-carbamic acid benzyl ester 

Relevant articles and documents

Design and reactivity of organic functional groups - Preparation and nucleophilic displacement reactions of imidazole-1-sulfonates (imidazylates)

Imidazole-1-sulfonate, a new type of leaving group by remote activation, allows facile S(N)2 substitution reactions at sterically crowded centers with various nucleophiles under mild conditions. It could be easily prepared from alcohols with cheap reagent

DESIGN AND REACTIVITY OF ORGANIC FUNCTIONAL GROUPS: IMIDAZOLYLSULFONATE (IMIDAZYLATE) - AN EFFICIENT AND VERSATILE LEAVING GROUP

The preparation and reactivity of the novel imidazolylsulfonate group is described.